pH-controlled synthesis of two new coordination polymers modeled by pyridine-2,4-dicarboxylic acid
文献类型：期刊论文
| 作者 | Meng FJ ; Jia HQ ; Hu NH ; Xu JW |
| 刊名 | inorganic chemistry communications
 |
| 出版日期 | 2012 |
| 卷号 | 21页码:186-190 |
| 关键词 | METAL-ORGANIC FRAMEWORKS HYDROTHERMAL SYNTHESIS COMPLEXES PHOTOLUMINESCENT CATALYSIS NETWORKS BRIDGES PYRIDINECARBOXYLATES SEPARATION BEHAVIOR |
| ISSN号 | 1387-7003 |
| 通讯作者 | hu nh |
| 中文摘要 | two new cadmium compounds [cd-3 (oh)(2) (2,4-pydc)(2)] (1) and [cd-2(2,4-pydc)(2)(bpe)]center dot 2h(2)o (2) (2,4-pydch(2)= pyridine-2,4-dicarboxylic acid, bpe=1,2-bis(4-pyridyl)ethene) have been prepared under hydrothermal conditions at different ph values. the compounds were characterized by elemental analyses, ir spectra and thermogravimetric analyses and their structures were determined by single-crystal x-ray diffraction analysis. compound 1 has a 3d framework constructed by 2d cd-o(oh) layers and pillared 2,4-pydc ligands. compound 2 also displays a 3d metal-organic framework with the cd(ii) centers connected by 2,4-pydc and bpe ligands. the differences in the structures indicate that the change of ph value has significant effects on the formation and structures of the final compounds. in addition, the luminescent properties of compounds 1-2 have also been studied. (c) 2012 elsevier b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000306614900047 |
| 公开日期 | 2013-05-20 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48062]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Meng FJ,Jia HQ,Hu NH,et al. pH-controlled synthesis of two new coordination polymers modeled by pyridine-2,4-dicarboxylic acid[J]. inorganic chemistry communications,2012,21:186-190. |
| APA | Meng FJ,Jia HQ,Hu NH,&Xu JW.(2012).pH-controlled synthesis of two new coordination polymers modeled by pyridine-2,4-dicarboxylic acid.inorganic chemistry communications,21,186-190. |
| MLA | Meng FJ,et al."pH-controlled synthesis of two new coordination polymers modeled by pyridine-2,4-dicarboxylic acid".inorganic chemistry communications 21(2012):186-190. |
入库方式： OAI收割
来源：长春应用化学研究所
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