An Efficient Suzuki-Miyaura Coupling of Aryl Sulfamates and Boronic Acids Catalyzed by NiCl2(dppp)
文献类型:期刊论文
作者 | Chen GJ ; Han FS |
刊名 | european journal of organic chemistry
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出版日期 | 2012 |
期号 | 19页码:3575-3579 |
关键词 | ARYLBORONIC ACIDS BIARYL CONSTRUCTION ROOM-TEMPERATURE NICKEL MESYLATES ARENESULFONATES ELECTROPHILES ACTIVATION HALIDES CARBOXYLATES |
ISSN号 | 1434-193x |
通讯作者 | han fs |
中文摘要 | the suzukimiyaura cross-coupling of aryl sulfamates and boronic acids was investigated by using [1,3-bis(diphenylphosphanyl)propane]nickel(ii) chloride {nicl2(dppp)} as the catalyst. the results showed that nicl2(dppp) is a highly active and general catalyst that allows effective suzukimiyaura cross-coupling of aryl sulfamates with a slight excess amount of the boronic acid (1.2 equiv.) in the presence of a low catalyst loading (generally 1.01.5 mol-%). the method also displays broad generality not only to various aryl sulfamates, but also to an array of boronic acids. furthermore, various functional groups are tolerated. these apparent advantages make nicl2(dppp) a practical and reliable catalyst system for the suzukimiyaura coupling of aryl sulfamates. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000305510400005 |
公开日期 | 2013-05-20 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48075] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Chen GJ,Han FS. An Efficient Suzuki-Miyaura Coupling of Aryl Sulfamates and Boronic Acids Catalyzed by NiCl2(dppp)[J]. european journal of organic chemistry,2012(19):3575-3579. |
APA | Chen GJ,&Han FS.(2012).An Efficient Suzuki-Miyaura Coupling of Aryl Sulfamates and Boronic Acids Catalyzed by NiCl2(dppp).european journal of organic chemistry(19),3575-3579. |
MLA | Chen GJ,et al."An Efficient Suzuki-Miyaura Coupling of Aryl Sulfamates and Boronic Acids Catalyzed by NiCl2(dppp)".european journal of organic chemistry .19(2012):3575-3579. |
入库方式: OAI收割
来源:长春应用化学研究所
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