Family of Diazapentalene Chromophores and Narrow-Band-Gap Polymers: Synthesis, Halochromism, Halofluorism, and Visible-Near Infrared Photodetectivity
文献类型：期刊论文
| 作者 | Qian G ; Qi J ; Davey JA ; Wright JS ; Wang ZY |
| 刊名 | chemistry of materials
 |
| 出版日期 | 2012 |
| 卷号 | 24期号:12页码:2364-2372 |
| 关键词 | HETEROJUNCTION SOLAR-CELLS LIGHT-EMITTING POLYMER THIN-FILM TRANSISTORS HIGH-DETECTIVITY ELECTRON FLUORESCENCE PERFORMANCE COPOLYMERS EFFICIENCY DYES |
| ISSN号 | 0897-4756 |
| 通讯作者 | wang zy |
| 中文摘要 | a family of pyrrolo[3,4-c]pyrrol-1(2h)-one (ppo) and 2,5-diazapentalene (dap) chromophores and dap-containing polymers were synthesized, and their optical and electrochemical properties were studied. ppo and dap chromophores are readily obtained by chemical transformation of the lactam unit in diketopyrrolopyrrole (dpp) dyes and can be used as versatile building blocks for construction of a variety of conjugated low-band-gap compounds and polymers. in comparison with the dpp chromophores, ppo and dap chromophores have narrower energy gaps and low-lying homo levels in the order dpp > ppo > dap. interestingly, the ppo and dap chromophores exhibit unique visible and near-infrared halochromic and halofluoric properties. the emission spectrum of dap-containing polymer 6d covers the telecommunication window including the wavelength of 1310 nm. the photodetector with a device configuration of ito/pedot:pss (35 nm)/active layer (100 nm)/al (100 nm) was fabricated using a blend of polymer 6d and [6,6]-phenyl-c-61-butyric acid methyl ester (pc61bm) in a weight ratio of 1:3 as the active layer and exhibited photocurrent spectral response from 400 to 1000 nm and the detectivity in an order of 10(11) jones at 800 nm. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000305662000017 |
| 公开日期 | 2013-05-20 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48088]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qian G,Qi J,Davey JA,et al. Family of Diazapentalene Chromophores and Narrow-Band-Gap Polymers: Synthesis, Halochromism, Halofluorism, and Visible-Near Infrared Photodetectivity[J]. chemistry of materials,2012,24(12):2364-2372. |
| APA | Qian G,Qi J,Davey JA,Wright JS,&Wang ZY.(2012).Family of Diazapentalene Chromophores and Narrow-Band-Gap Polymers: Synthesis, Halochromism, Halofluorism, and Visible-Near Infrared Photodetectivity.chemistry of materials,24(12),2364-2372. |
| MLA | Qian G,et al."Family of Diazapentalene Chromophores and Narrow-Band-Gap Polymers: Synthesis, Halochromism, Halofluorism, and Visible-Near Infrared Photodetectivity".chemistry of materials 24.12(2012):2364-2372. |
入库方式： OAI收割
来源：长春应用化学研究所
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