Yttrium Hydride Complex Bearing CpPN/Amidinate Heteroleptic Ligands: Synthesis, Structure, and Reactivity
文献类型：期刊论文
| 作者 | Jian ZB ; Hangaly NK ; Rong WF ; Mou ZH ; Liu DT ; Li SH ; Trifonov AA ; Sundermeyer J ; Cui DM |
| 刊名 | organometallics
 |
| 出版日期 | 2012 |
| 卷号 | 31期号:12页码:4579-4587 |
| 关键词 | EARTH-METAL COMPLEXES RAY CRYSTALLOGRAPHIC CHARACTERIZATION 4-COORDINATE HYDROGEN-ATOM H BOND ACTIVATION POLYMERIZATION CATALYSTS LINKED CYCLOPENTADIENYL POLYHYDRIDO COMPLEXES LANTHANIDE COMPLEXES ANCILLARY LIGAND MONO(CYCLOPENTADIENYL) LIGANDS |
| ISSN号 | 0276-7333 |
| 通讯作者 | sundermeyer j |
| 中文摘要 | the reaction of the yttrium dialkyls (c5h4- pph2=n (c6h3pr2)-pr-i)y(ch2sime3)(2)(thf) (1) with an excess of n,n'-diisopropylcarbodiimide gave the yttrium monoalkyl complex (c5h4-pph2=n-(c6h3pr2)-pr-i)y(ch2sime3)[(prn)-pr-i= c(ch2sime3)-(npr)-pr-i] (2). 2 subsequently reacted with 1 equiv of phsih3 to generate the cppn/amidinate heteroleptic yttrium hydride [(c5h4-pph2=n (c6h3pr2)-pr-i)y(ch2sime3)(2)-(npr)-pr-i](mu-h)}(2) (3). hydride 3 showed good reactivity toward various substrates containing unsaturated c c, c-n, and n-n bonds, such as azobenzene, p-tolyacetylene, 1,4-bis(trimethylsily1)-1,3-butanediyne, n,n'-diisopropylcarbodiimide, and 4-dimethylaminopyridine, affording the yttrium hydrazide complex 4 with a rare eta(2)-cp bonding mode, yttrium terminal alkynyl complex 5, yttrium eta(3)-propargyl complex 6, yttrium amidinate complex 7, and yttrium 2-hydro-4-dimethylaminopyridyl product 8, respectively. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000305588000025 |
| 公开日期 | 2013-05-20 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48091]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Jian ZB,Hangaly NK,Rong WF,et al. Yttrium Hydride Complex Bearing CpPN/Amidinate Heteroleptic Ligands: Synthesis, Structure, and Reactivity[J]. organometallics,2012,31(12):4579-4587. |
| APA | Jian ZB.,Hangaly NK.,Rong WF.,Mou ZH.,Liu DT.,...&Cui DM.(2012).Yttrium Hydride Complex Bearing CpPN/Amidinate Heteroleptic Ligands: Synthesis, Structure, and Reactivity.organometallics,31(12),4579-4587. |
| MLA | Jian ZB,et al."Yttrium Hydride Complex Bearing CpPN/Amidinate Heteroleptic Ligands: Synthesis, Structure, and Reactivity".organometallics 31.12(2012):4579-4587. |
入库方式： OAI收割
来源：长春应用化学研究所
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