Establishment of rapid detection method of methamidophos in vegetables by surface enhanced Raman spectroscopy
文献类型:期刊论文
作者 | Xie YF ; Mukamurezi G ; Sun YY ; Wang HY ; Qian H ; Yao WR |
刊名 | european food research and technology
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出版日期 | 2012 |
卷号 | 234期号:6页码:1091-1098 |
关键词 | SCATTERING SILVER PH |
ISSN号 | 1438-2377 |
通讯作者 | yao wr |
中文摘要 | methamidophos (map) is a highly efficient and broad-spectrum organophosphate pesticide. in this study, a rapid method for detecting map in vegetables using surface enhanced raman scattering (sers) spectroscopy has been established. density functional theory calculations were performed with gaussian 03 at rb3lyp level and with the 6-311g (d) basis set. sers, normal and theoretical raman spectroscopy were compared to investigate the mechanism of raman scattering enhancement. the sers signal of map was improved in alkaline conditions with optimum scattering efficiency at ph of 13.46. furthermore, map detection in vegetables by sers method had a good linear relationship between 0.01 and 1,000 mu g/ml. the concentration of map in vegetables was detected and chosen for recovery test with three levels: 4, 8, and 15 mu g/ml. the results of three level tests were 86.7-96.6 % and their relative standard deviations were between 1.2 and 2.5 %, which shows the good repeatability of this method. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000304162600019 |
公开日期 | 2013-05-20 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48125] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Xie YF,Mukamurezi G,Sun YY,et al. Establishment of rapid detection method of methamidophos in vegetables by surface enhanced Raman spectroscopy[J]. european food research and technology,2012,234(6):1091-1098. |
APA | Xie YF,Mukamurezi G,Sun YY,Wang HY,Qian H,&Yao WR.(2012).Establishment of rapid detection method of methamidophos in vegetables by surface enhanced Raman spectroscopy.european food research and technology,234(6),1091-1098. |
MLA | Xie YF,et al."Establishment of rapid detection method of methamidophos in vegetables by surface enhanced Raman spectroscopy".european food research and technology 234.6(2012):1091-1098. |
入库方式: OAI收割
来源:长春应用化学研究所
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