中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Establishment of rapid detection method of methamidophos in vegetables by surface enhanced Raman spectroscopy

文献类型:期刊论文

作者Xie YF ; Mukamurezi G ; Sun YY ; Wang HY ; Qian H ; Yao WR
刊名european food research and technology
出版日期2012
卷号234期号:6页码:1091-1098
关键词SCATTERING SILVER PH
ISSN号1438-2377
通讯作者yao wr
中文摘要methamidophos (map) is a highly efficient and broad-spectrum organophosphate pesticide. in this study, a rapid method for detecting map in vegetables using surface enhanced raman scattering (sers) spectroscopy has been established. density functional theory calculations were performed with gaussian 03 at rb3lyp level and with the 6-311g (d) basis set. sers, normal and theoretical raman spectroscopy were compared to investigate the mechanism of raman scattering enhancement. the sers signal of map was improved in alkaline conditions with optimum scattering efficiency at ph of 13.46. furthermore, map detection in vegetables by sers method had a good linear relationship between 0.01 and 1,000 mu g/ml. the concentration of map in vegetables was detected and chosen for recovery test with three levels: 4, 8, and 15 mu g/ml. the results of three level tests were 86.7-96.6 % and their relative standard deviations were between 1.2 and 2.5 %, which shows the good repeatability of this method.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000304162600019
公开日期2013-05-20
源URL[http://ir.ciac.jl.cn/handle/322003/48125]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Xie YF,Mukamurezi G,Sun YY,et al. Establishment of rapid detection method of methamidophos in vegetables by surface enhanced Raman spectroscopy[J]. european food research and technology,2012,234(6):1091-1098.
APA Xie YF,Mukamurezi G,Sun YY,Wang HY,Qian H,&Yao WR.(2012).Establishment of rapid detection method of methamidophos in vegetables by surface enhanced Raman spectroscopy.european food research and technology,234(6),1091-1098.
MLA Xie YF,et al."Establishment of rapid detection method of methamidophos in vegetables by surface enhanced Raman spectroscopy".european food research and technology 234.6(2012):1091-1098.

入库方式: OAI收割

来源:长春应用化学研究所

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