Preparation and thermophysical properties of nano-sized Ln(2)Zr(2)O(7) (Ln = La, Nd, Sm, and Gd) ceramics with pyrochlore structure
文献类型:期刊论文
作者 | Wang CJ ; Wang Y ; Cheng YL ; Huang WZ ; Khan ZS ; Fan XZ ; Wang Y ; Zou BL ; Cao XQ |
刊名 | journal of materials science
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出版日期 | 2012 |
卷号 | 47期号:10页码:4392-4399 |
关键词 | YTTRIA-STABILIZED ZIRCONIA OXIDE TI |
ISSN号 | 0022-2461 |
通讯作者 | cao xq |
中文摘要 | rare earth zirconates (ln(2)zr(2)o(7), ln = la, nd, sm, and gd) with pyrochlore structure were prepared by hydrothermal method with polyethylene glycol as surfactant. x-ray diffraction, thermogravimetric analysis/differential scanning calorimetry, fourier transform infrared spectroscopy, raman spectroscopy, and field emission scanning electron microscopy were utilized to characterize the phase structure, thermal decomposition, and morphology of the products. qualitative analysis indicates that the as-prepared zirconates are pyrochlore-type structures. the specific surface area, lattice parameter, and average crystallite size of the as-prepared products are closely related to the ionic radius. the activation energy of crystal growth shows an increasing trend with the decrease in ionic radii. the sintering behavior of compacted body was also investigated, revealing that the sintering-resistance properties of ln(2)zr(2)o(7) are descending as the order of la2zr2o7, nd2zr2o7, sm2zr2o7, and gd2zr2o7. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000302242700019 |
公开日期 | 2013-05-22 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48202] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Wang CJ,Wang Y,Cheng YL,et al. Preparation and thermophysical properties of nano-sized Ln(2)Zr(2)O(7) (Ln = La, Nd, Sm, and Gd) ceramics with pyrochlore structure[J]. journal of materials science,2012,47(10):4392-4399. |
APA | Wang CJ.,Wang Y.,Cheng YL.,Huang WZ.,Khan ZS.,...&Cao XQ.(2012).Preparation and thermophysical properties of nano-sized Ln(2)Zr(2)O(7) (Ln = La, Nd, Sm, and Gd) ceramics with pyrochlore structure.journal of materials science,47(10),4392-4399. |
MLA | Wang CJ,et al."Preparation and thermophysical properties of nano-sized Ln(2)Zr(2)O(7) (Ln = La, Nd, Sm, and Gd) ceramics with pyrochlore structure".journal of materials science 47.10(2012):4392-4399. |
入库方式: OAI收割
来源:长春应用化学研究所
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