Solution-Phase Electronegativity Scale: Insight into the Chemical Behaviors of Metal Ions in Solution
文献类型：期刊论文
| 作者 | Li KY ; Li M ; Xue DF |
| 刊名 | journal of physical chemistry a
 |
| 出版日期 | 2012 |
| 卷号 | 116期号:16页码:4192-4198 |
| ISSN号 | 1089-5639 |
| 关键词 | FREE-ENERGIES AQUEOUS-SOLUTION GAS-PHASE HYDROLYSIS SOLVENT MODEL CONSTANTS HYDRATION ELEMENTS HARDNESS |
| 通讯作者 | xue df |
| 中文摘要 | by incorporating the solvent effect into the born effective radius, we have proposed an electronegativity scale of metal ions in aqueous solution with the most common oxidation states and hydration coordination numbers in terms of the effective ionic electrostatic potential. it is found that the metal ions in aqueous solution are poorer electron acceptors compared to those in the gas phase. this solution-phase electronegativity scale shows its efficiency in predicting some important properties of metal ions in aqueous solution such as the aqueous acidities of the metal ions, the stability constants of metal complexes, and the solubility product constants of the metal hydroxides. we have elaborated that the standard reduction potential and the solution-phase electronegativity are two different quantities for describing the processes of metal ions in aqueous solution to soak up electrons with different final states. this work provides a new insight into the chemical behaviors of the metal ions in aqueous solution, indicating a potential application of this electronegativity scale to the design of solution reactions. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000303173700024 |
| 公开日期 | 2013-05-22 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48207]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li KY,Li M,Xue DF. Solution-Phase Electronegativity Scale: Insight into the Chemical Behaviors of Metal Ions in Solution[J]. journal of physical chemistry a,2012,116(16):4192-4198. |
| APA | Li KY,Li M,&Xue DF.(2012).Solution-Phase Electronegativity Scale: Insight into the Chemical Behaviors of Metal Ions in Solution.journal of physical chemistry a,116(16),4192-4198. |
| MLA | Li KY,et al."Solution-Phase Electronegativity Scale: Insight into the Chemical Behaviors of Metal Ions in Solution".journal of physical chemistry a 116.16(2012):4192-4198. |
入库方式： OAI收割
来源：长春应用化学研究所
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