Synthesis and up-conversion white light emission of RE3+-doped lutetium oxide nanocubes as a single compound
文献类型:期刊论文
作者 | Hu SS ; Yang J ; Li CX ; Lin J |
刊名 | materials chemistry and physics
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出版日期 | 2012 |
卷号 | 133期号:2-3页码:751-756 |
关键词 | MEDIATED HYDROTHERMAL SYNTHESIS LUMINESCENCE PROPERTIES ENERGY-TRANSFER CDSE NANOCRYSTALS Y2O3 NANOCRYSTALS THIN-FILMS GREEN YB3+ BLUE RED |
ISSN号 | 0254-0584 |
通讯作者 | yang j |
中文摘要 | uniform and dispersive lu2o3:yb3+/er3+/tm3+ nanocubes have been successfully synthesized by hydrothermal process with subsequent calcination at 900 degrees c. the as-formed re3+-doped lutetium oxide precursor via the hydrothermal process, as a template, could transform to re3+-doped lu2o3 with their original cubic morphology and slight shrinkage in the size after post-annealing process. the formation mechanism for the lutetium oxide precursor cubes has been proposed. under single wavelength diode laser excitation of 980 nm, the as-obtained lu2o3:3%yb3+/0.5%er3+/03%tm3+ nanocubes show nearly equal intensities of blue (tm3+: (1)g(4) -> h-3(6)), green (er3+: (h-2(11/2), s-4(3/2)) -> i-4(15/2)), and red (er3+: f-4(9/2) -> i-4(15/2)) emissions, which produces bright white light emission, clearly visible to the naked eyes. the main pathways to populate the upper emitting states come from the energy-transfer processes from yb3+ to tm3+/er3+, respectively. the chromaticity coordinate of the lu2o3:3%yb3+/0.5%er3+/0.3%tm3+ sample is calculated to be about x = 0.3403 and y = 03169, which falls exactly within the white region of 1931 cie diagram and is very close to the standard equal energy white light illuminate (x = 0.33 and y = 0.33), pointing out its potential use as a white light source under 980 nm laser diode excitation. (c) 2012 elsevier b.v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000303281500029 |
公开日期 | 2013-05-22 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48217] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Hu SS,Yang J,Li CX,et al. Synthesis and up-conversion white light emission of RE3+-doped lutetium oxide nanocubes as a single compound[J]. materials chemistry and physics,2012,133(2-3):751-756. |
APA | Hu SS,Yang J,Li CX,&Lin J.(2012).Synthesis and up-conversion white light emission of RE3+-doped lutetium oxide nanocubes as a single compound.materials chemistry and physics,133(2-3),751-756. |
MLA | Hu SS,et al."Synthesis and up-conversion white light emission of RE3+-doped lutetium oxide nanocubes as a single compound".materials chemistry and physics 133.2-3(2012):751-756. |
入库方式: OAI收割
来源:长春应用化学研究所
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