Novel Functional Organic Network Containing Quaternary Phosphonium and Tertiary Phosphorus
文献类型：期刊论文
| 作者 | Zhang Q ; Zhang SB ; Li SH |
| 刊名 | macromolecules
 |
| 出版日期 | 2012 |
| 卷号 | 45期号:7页码:2981-2988 |
| 关键词 | HIGH-SURFACE-AREA INTRINSIC MICROPOROSITY PIMS HETEROGENEOUS CATALYSIS THIN-FILMS POLYMERS FRAMEWORKS POROSITY GAS PHTHALOCYANINE NANOPARTICLES |
| ISSN号 | 0024-9297 |
| 通讯作者 | zhang sb |
| 中文摘要 | a quaternary phosphonium and tertiary phosphorus functionalized microporous polymer was obtained via nickel(0)-catalyzed yamamoto-type cross-coupling reaction. the integration ratio of signals (quaternary phosphonium to tertiary phosphorus atoms) was close to 3:2. the polymer networks were stable toward water, base, and acid, and indeed no change in surface area was observed even after the material was treated with 10 m hcl. the pore size distribution calculated by the horvath-kawazoe method indicated the presence of micropores with a mean width of about 0.7 and 1.4 nm. their apparent bet specific surface areas can be tuned (from 650 to 980 m(2) g(-1)) by changing the counteranions (br- to f-). it displays high intrinsic catalytic activity for the reaction between epoxide and co2 (yield: 98%, 1 atm). pd nanopartides supported on the polymer networks were also prepared, which exhibits high catalytic activity for cross-coupling reaction between 1-chlorobenzene and phenylboronic acid (yield: >95.8%). |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000302511500005 |
| 公开日期 | 2013-05-22 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48231]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang Q,Zhang SB,Li SH. Novel Functional Organic Network Containing Quaternary Phosphonium and Tertiary Phosphorus[J]. macromolecules,2012,45(7):2981-2988. |
| APA | Zhang Q,Zhang SB,&Li SH.(2012).Novel Functional Organic Network Containing Quaternary Phosphonium and Tertiary Phosphorus.macromolecules,45(7),2981-2988. |
| MLA | Zhang Q,et al."Novel Functional Organic Network Containing Quaternary Phosphonium and Tertiary Phosphorus".macromolecules 45.7(2012):2981-2988. |
入库方式： OAI收割
来源：长春应用化学研究所
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