中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effective Solid Contact for Ion-Selective Electrodes: Tetrakis(4-chlorophenyl)borate (TB-) Anions Doped Nanocluster Films

文献类型:期刊论文

作者Zhou M ; Gan SY ; Cai B ; Li FH ; Ma WG ; Han DX ; Niu L
刊名analytical chemistry
出版日期2012
卷号84期号:7页码:3480-3483
关键词IMMOBILIZED GOLD NANOCLUSTERS SELF-ASSEMBLED MONOLAYERS NANOPARTICLE ASSEMBLIES CONDUCTING POLYMERS AQUEOUS-MEDIA MEMBRANE STATE CLUSTERS SENSORS TRANSDUCERS
ISSN号0003-2700
通讯作者niu l
中文摘要we report on a novel material, tetrakis(4-chlorophenyl)borate (tb-) anion doped nanocluster films, as the solid contact (sc) for producing well-defined, electrochemically reversible, and nonpolarizable double interfaces on it. detailed studies have unambiguously revealed that, for the first time, the developed sc can fully overcome all the signal stability problems of ion-selective electrodes (ises), offering a reliable and universal platform for the development of high quality sc-ises. as an exemplification, the developed monolayer-protected cluster (mpc) based k+-ises have advantages of excellent analytical performances, e.g., the low potential drift (10.1 +/- 0.3 mu v h(-1) over 72 h measured in 0.1 m kcl and 10.8 +/- 0.5 mu v h(-1) over 96 h rechecked in 0.1 m kcl after 1 month) and the stable and reproducible linear range, sensitivity, and standard potential (few changes within the first 6 weeks). this evidence suggests that the developed mpc films are the most promising sc transducers among all the reported ones to the best of our knowledge.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000302829800063
公开日期2013-05-22
源URL[http://ir.ciac.jl.cn/handle/322003/48236]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Zhou M,Gan SY,Cai B,et al. Effective Solid Contact for Ion-Selective Electrodes: Tetrakis(4-chlorophenyl)borate (TB-) Anions Doped Nanocluster Films[J]. analytical chemistry,2012,84(7):3480-3483.
APA Zhou M.,Gan SY.,Cai B.,Li FH.,Ma WG.,...&Niu L.(2012).Effective Solid Contact for Ion-Selective Electrodes: Tetrakis(4-chlorophenyl)borate (TB-) Anions Doped Nanocluster Films.analytical chemistry,84(7),3480-3483.
MLA Zhou M,et al."Effective Solid Contact for Ion-Selective Electrodes: Tetrakis(4-chlorophenyl)borate (TB-) Anions Doped Nanocluster Films".analytical chemistry 84.7(2012):3480-3483.

入库方式: OAI收割

来源:长春应用化学研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。