Effective Solid Contact for Ion-Selective Electrodes: Tetrakis(4-chlorophenyl)borate (TB-) Anions Doped Nanocluster Films
文献类型:期刊论文
作者 | Zhou M ; Gan SY ; Cai B ; Li FH ; Ma WG ; Han DX ; Niu L |
刊名 | analytical chemistry
![]() |
出版日期 | 2012 |
卷号 | 84期号:7页码:3480-3483 |
关键词 | IMMOBILIZED GOLD NANOCLUSTERS SELF-ASSEMBLED MONOLAYERS NANOPARTICLE ASSEMBLIES CONDUCTING POLYMERS AQUEOUS-MEDIA MEMBRANE STATE CLUSTERS SENSORS TRANSDUCERS |
ISSN号 | 0003-2700 |
通讯作者 | niu l |
中文摘要 | we report on a novel material, tetrakis(4-chlorophenyl)borate (tb-) anion doped nanocluster films, as the solid contact (sc) for producing well-defined, electrochemically reversible, and nonpolarizable double interfaces on it. detailed studies have unambiguously revealed that, for the first time, the developed sc can fully overcome all the signal stability problems of ion-selective electrodes (ises), offering a reliable and universal platform for the development of high quality sc-ises. as an exemplification, the developed monolayer-protected cluster (mpc) based k+-ises have advantages of excellent analytical performances, e.g., the low potential drift (10.1 +/- 0.3 mu v h(-1) over 72 h measured in 0.1 m kcl and 10.8 +/- 0.5 mu v h(-1) over 96 h rechecked in 0.1 m kcl after 1 month) and the stable and reproducible linear range, sensitivity, and standard potential (few changes within the first 6 weeks). this evidence suggests that the developed mpc films are the most promising sc transducers among all the reported ones to the best of our knowledge. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000302829800063 |
公开日期 | 2013-05-22 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48236] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhou M,Gan SY,Cai B,et al. Effective Solid Contact for Ion-Selective Electrodes: Tetrakis(4-chlorophenyl)borate (TB-) Anions Doped Nanocluster Films[J]. analytical chemistry,2012,84(7):3480-3483. |
APA | Zhou M.,Gan SY.,Cai B.,Li FH.,Ma WG.,...&Niu L.(2012).Effective Solid Contact for Ion-Selective Electrodes: Tetrakis(4-chlorophenyl)borate (TB-) Anions Doped Nanocluster Films.analytical chemistry,84(7),3480-3483. |
MLA | Zhou M,et al."Effective Solid Contact for Ion-Selective Electrodes: Tetrakis(4-chlorophenyl)borate (TB-) Anions Doped Nanocluster Films".analytical chemistry 84.7(2012):3480-3483. |
入库方式: OAI收割
来源:长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。