Lanthanide Anionic Metal-Organic Frameworks Containing Semirigid Tetracarboxylate Ligands: Structure, Photoluminescence, and Magnetism
文献类型：期刊论文
| 作者 | Su SQ ; Chen W ; Qin C ; Song SY ; Guo ZY ; Li GH ; Song XZ ; Zhu M ; Wang S ; Hao ZM ; Zhang HJ |
| 刊名 | crystal growth & design
 |
| 出版日期 | 2012 |
| 卷号 | 12期号:4页码:1808-1815 |
| 关键词 | EARTH COORDINATION POLYMERS METHYLENEDIISOPHTHALIC ACID H4MDIP NEAR-INFRARED EMISSION LUMINESCENT PROPERTIES CRYSTAL-STRUCTURES SORPTION PROPERTIES BUILDING UNITS GAS-ADSORPTION HELICAL CHAINS COMPLEXES |
| ISSN号 | 1528-7483 |
| 通讯作者 | zhang hj |
| 中文摘要 | a series of lanthanide anionic metal-organic frameworks, [nh2(ch3)(2)][ln(mdip)(h2o)] (ln = pr (1), nd (2), sm (3), eu (4), gd (5), tb (6), dy (7); h4mdip = methylenediisophthalic acid) and [nh2(ch3)(2)][ln(mdip)(h2o)]center dot 0.5nh(ch3)(2) (ln = er (8), tm (9), yb (10)), have been synthesized and characterized. in compounds 1-7, the adjacent ln(3+) ions are intraconnected to form infinite metal-carboxylate oxygen chain-shaped building blocks along the [001] direction. in compounds 8-10, mdip ligands bridge dinuclear lanthanide centers to form three-dimensional frameworks which can be rationalized as a (4,8)-connected topological net with the schlafli symbol of (4(10).6(14).8(4))(4(5).6)(2). dimethylamine cations occupy the vacancy of all the compounds as counterions. the photophysical properties of trivalent pr, nd, sm, eu, tb, dy, er, yb compounds at temperature were investigated and showed that mdip is an efficient sensitizer of the luminescence of both the tb3+ ion emitting visible light and the yb3+. ion emitting in the near-ir antiferromagnetic interactions between gd3+ ions were observed from magnetic susceptibility data. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000302336900015 |
| 公开日期 | 2013-06-03 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48250]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Su SQ,Chen W,Qin C,et al. Lanthanide Anionic Metal-Organic Frameworks Containing Semirigid Tetracarboxylate Ligands: Structure, Photoluminescence, and Magnetism[J]. crystal growth & design,2012,12(4):1808-1815. |
| APA | Su SQ.,Chen W.,Qin C.,Song SY.,Guo ZY.,...&Zhang HJ.(2012).Lanthanide Anionic Metal-Organic Frameworks Containing Semirigid Tetracarboxylate Ligands: Structure, Photoluminescence, and Magnetism.crystal growth & design,12(4),1808-1815. |
| MLA | Su SQ,et al."Lanthanide Anionic Metal-Organic Frameworks Containing Semirigid Tetracarboxylate Ligands: Structure, Photoluminescence, and Magnetism".crystal growth & design 12.4(2012):1808-1815. |
入库方式： OAI收割
来源：长春应用化学研究所
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