Phenyltrimethylammonium Functionalized Polysulfone Anion Exchange Membranes
文献类型：期刊论文
| 作者 | Li N ; Zhang Q ; Wang CY ; Lee YM ; Guiver MD |
| 刊名 | macromolecules
 |
| 出版日期 | 2012 |
| 卷号 | 45期号:5页码:2411-2419 |
| 关键词 | FUEL-CELL APPLICATIONS QUATERNARY PHOSPHONIUM HYDROXIDES POLY(ARYLENE ETHER SULFONE) POLYMER ELECTROLYTE CHEMICAL-MODIFICATION TRANSPORT-PROPERTIES SIDE-CHAINS ACID GROUPS PERFORMANCE SUBSTITUENTS |
| ISSN号 | 0024-9297 |
| 通讯作者 | lee ym |
| 中文摘要 | anion exchange membrane (aem) materials were prepared from commercial polysulfone (psf) by functionalization with tertiary amines via lithiation chemistry. by optimizing the reaction conditions, a degree of substitution (ds) of 0.81 could be achieved without evident polymer decomposition or cross-linking. the psf containing pendent bis(phenyldimethylamine) substituents were then quatemized with ch3i and ion exchange reaction to provide bis(phenyltrimethylammonium) (ptma) polymer with hydroxide-conductive properties. flexible and tough membranes with various ion exchange capacities (iec)s could be prepared by casting the polymers from dmac solutions. the ionomeric membranes showed considerably lower water uptake (less than 20%), and thus dimensional swelling in water, compared with many reported aems. the hydroxide conductivities of the membranes were above 10 ms/cm at room temperature. the unusually low water uptake and good hydroxide conductivity may be attributed to the "side-chain-type" structures of pendent functional groups, which facilitate ion transport. although the ptma substituents on the aem were found to have insufficient long-term stability for alkaline fuel cell application, the investigation gives some insight and directions for polymeric designs by postfunctionalization. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000301397800027 |
| 公开日期 | 2013-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48272]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li N,Zhang Q,Wang CY,et al. Phenyltrimethylammonium Functionalized Polysulfone Anion Exchange Membranes[J]. macromolecules,2012,45(5):2411-2419. |
| APA | Li N,Zhang Q,Wang CY,Lee YM,&Guiver MD.(2012).Phenyltrimethylammonium Functionalized Polysulfone Anion Exchange Membranes.macromolecules,45(5),2411-2419. |
| MLA | Li N,et al."Phenyltrimethylammonium Functionalized Polysulfone Anion Exchange Membranes".macromolecules 45.5(2012):2411-2419. |
入库方式： OAI收割
来源：长春应用化学研究所
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