Aerobic Oxidations of C-60(2-) in the Presence of PhCN and PhCH2CN: Oxygenation versus Dehydrogenation Reactions
文献类型：期刊论文
| 作者 | Hou HL ; Gao X |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2012 |
| 卷号 | 77期号:5页码:2553-2558 |
| 关键词 | ELECTRON-TRANSFER SUPEROXIDE ANION FULLERENE C-60 ELECTROSYNTHESIS GENERATION ACIDITIES ALKOXIDES |
| ISSN号 | 0022-3263 |
| 通讯作者 | gao x |
| 中文摘要 | aerobic oxidations of dianionic c-60 were examined in phcn and phch2cn, where dioxygen was activated to o-2(center dot-) via the single-electron transfer from c-60(2-) and underwent oxygenation and dehydrogenation reactions, respectively. addition of phch2br led to further benzylation for the oxygenated product but not for the dehydrogenated one, suggesting that the initial two negative charges were preserved for the intermediates of the oxygenation reaction but not for those of the dehydrogenation reaction. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000300915900053 |
| 公开日期 | 2013-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48281]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Hou HL,Gao X. Aerobic Oxidations of C-60(2-) in the Presence of PhCN and PhCH2CN: Oxygenation versus Dehydrogenation Reactions[J]. journal of organic chemistry,2012,77(5):2553-2558. |
| APA | Hou HL,&Gao X.(2012).Aerobic Oxidations of C-60(2-) in the Presence of PhCN and PhCH2CN: Oxygenation versus Dehydrogenation Reactions.journal of organic chemistry,77(5),2553-2558. |
| MLA | Hou HL,et al."Aerobic Oxidations of C-60(2-) in the Presence of PhCN and PhCH2CN: Oxygenation versus Dehydrogenation Reactions".journal of organic chemistry 77.5(2012):2553-2558. |
入库方式： OAI收割
来源：长春应用化学研究所
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