Synthesis of Densely Substituted alpha,beta,gamma, delta-Dienones via the Pd-II-Catalyzed Allylation, H-Migration, and Aerobic Oxidative delta-Hydride Elimination Cascade
文献类型：期刊论文
| 作者 | Yuan FQ ; Han FS |
| 刊名 | organic letters
 |
| 出版日期 | 2012 |
| 卷号 | 14期号:5页码:1218-1221 |
| 关键词 | CROSS-COUPLING REACTION 1 HETEROAROMATIC-COMPOUNDS 3-BUTADIENES ALLYLIC ALKYLATION GRIGNARD-REAGENTS OLEFINATION ALDEHYDES EFFICIENT ALKENES DERIVATIVES |
| ISSN号 | 1523-7060 |
| 通讯作者 | han fs |
| 中文摘要 | a novel protocol for the highly stereoselective synthesis of e,e-alpha,beta,gamma,delta-unsaturated dicarbonyl compounds is presented. starting from the readily available allylic alcohols and 1,3-cliketones, an array of e,e-alpha,beta,gamma,delta-dienones can be efficiently synthesized in high yields via pd-catalyzed dehydrative allylation, h-migration, and aerobic oxidative 6-hydride elimination cascade. in addition to the novel reaction mechanism, the use of 1:1 allylic alcohol and 1,3-diketone as reactant, 5 mol % of pdcl2 as catalyst, and 1 atm of environmentally benign 02 as oxidant, as well as the generation of only h2o byproduct, makes this protocol rapid, simple, atom-efficient, and clean. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000300916000009 |
| 公开日期 | 2013-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48282]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yuan FQ,Han FS. Synthesis of Densely Substituted alpha,beta,gamma, delta-Dienones via the Pd-II-Catalyzed Allylation, H-Migration, and Aerobic Oxidative delta-Hydride Elimination Cascade[J]. organic letters,2012,14(5):1218-1221. |
| APA | Yuan FQ,&Han FS.(2012).Synthesis of Densely Substituted alpha,beta,gamma, delta-Dienones via the Pd-II-Catalyzed Allylation, H-Migration, and Aerobic Oxidative delta-Hydride Elimination Cascade.organic letters,14(5),1218-1221. |
| MLA | Yuan FQ,et al."Synthesis of Densely Substituted alpha,beta,gamma, delta-Dienones via the Pd-II-Catalyzed Allylation, H-Migration, and Aerobic Oxidative delta-Hydride Elimination Cascade".organic letters 14.5(2012):1218-1221. |
入库方式： OAI收割
来源：长春应用化学研究所
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