Diversity of Lanthanide(III)-Organic Extended Frameworks with a 4,8-Disulfonyl-2,6-naphthalenedicarboxylic Acid Ligand: Syntheses, Structures, and Magnetic and Luminescent Properties
文献类型:期刊论文
作者 | Liu QY ; Wang WF ; Wang YL ; Shan ZM ; Wang MS ; Tang JK |
刊名 | inorganic chemistry
![]() |
出版日期 | 2012 |
卷号 | 51期号:4页码:2381-2392 |
关键词 | METAL-ORGANIC FRAMEWORKS ASSISTED HYDROGEN-BONDS SINGLE-MOLECULE MAGNET COORDINATION POLYMER CRYSTAL-STRUCTURES HYDROTHERMAL SYNTHESIS FLUORESCENCE-SPECTRA COMPLEXES SOLIDS SERIES |
ISSN号 | 0020-1669 |
通讯作者 | liu qy |
中文摘要 | a sulfonate-carboxylate ligand, 4,8-disulfonyl-2,6-naphthalenedicarboxylic acid (h-4-dsnda), and eight new lanthanide coordination polymers {[pr-4(oh)(4)(dsnda)(2)(h2o)(12)](h2o)(10)}(n) (1), [ln(h-2-dsnda)(0.5)(dsnda)(0.5)(h2o)(5)](n) (ln = la(2), nd(3), sm(4), eu(5), gd(6), and dy(7)), and {[er(h-dsnda)(h2o)(4)](h2o)}(n) (8) have been synthesized. detailed crystal structures of these compounds have been investigated. compound 1 has a 3d framework featuring the unique cubane-shaped [pr-4(mu(3)-oh)(4)] clusters and is a binodal 4,8-connected network with (4(16).6(12))(4(4).6(2))(2) topology. compounds 2-7 are isostructural and have 2d layered structures. compound 8 is also a 2d layer but belongs to different structural types. the luminescence behavior of compound eu(5) shows that the pi-rich aromatic organic ligands efficiently transfer the absorbed light energy to the eu(iii) ions, thus enhancing the overall luminescent properties of compound eu(5). the magnetic properties of all compounds except for the diamagnetic la(2) compound have been investigated. in addition, elemental analysis, ir spectra, and thermogravimetric analysis of these compounds are also described. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000300466300051 |
公开日期 | 2013-06-08 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48312] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Liu QY,Wang WF,Wang YL,et al. Diversity of Lanthanide(III)-Organic Extended Frameworks with a 4,8-Disulfonyl-2,6-naphthalenedicarboxylic Acid Ligand: Syntheses, Structures, and Magnetic and Luminescent Properties[J]. inorganic chemistry,2012,51(4):2381-2392. |
APA | Liu QY,Wang WF,Wang YL,Shan ZM,Wang MS,&Tang JK.(2012).Diversity of Lanthanide(III)-Organic Extended Frameworks with a 4,8-Disulfonyl-2,6-naphthalenedicarboxylic Acid Ligand: Syntheses, Structures, and Magnetic and Luminescent Properties.inorganic chemistry,51(4),2381-2392. |
MLA | Liu QY,et al."Diversity of Lanthanide(III)-Organic Extended Frameworks with a 4,8-Disulfonyl-2,6-naphthalenedicarboxylic Acid Ligand: Syntheses, Structures, and Magnetic and Luminescent Properties".inorganic chemistry 51.4(2012):2381-2392. |
入库方式: OAI收割
来源:长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。