中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Diversity of Lanthanide(III)-Organic Extended Frameworks with a 4,8-Disulfonyl-2,6-naphthalenedicarboxylic Acid Ligand: Syntheses, Structures, and Magnetic and Luminescent Properties

文献类型:期刊论文

作者Liu QY ; Wang WF ; Wang YL ; Shan ZM ; Wang MS ; Tang JK
刊名inorganic chemistry
出版日期2012
卷号51期号:4页码:2381-2392
关键词METAL-ORGANIC FRAMEWORKS ASSISTED HYDROGEN-BONDS SINGLE-MOLECULE MAGNET COORDINATION POLYMER CRYSTAL-STRUCTURES HYDROTHERMAL SYNTHESIS FLUORESCENCE-SPECTRA COMPLEXES SOLIDS SERIES
ISSN号0020-1669
通讯作者liu qy
中文摘要a sulfonate-carboxylate ligand, 4,8-disulfonyl-2,6-naphthalenedicarboxylic acid (h-4-dsnda), and eight new lanthanide coordination polymers {[pr-4(oh)(4)(dsnda)(2)(h2o)(12)](h2o)(10)}(n) (1), [ln(h-2-dsnda)(0.5)(dsnda)(0.5)(h2o)(5)](n) (ln = la(2), nd(3), sm(4), eu(5), gd(6), and dy(7)), and {[er(h-dsnda)(h2o)(4)](h2o)}(n) (8) have been synthesized. detailed crystal structures of these compounds have been investigated. compound 1 has a 3d framework featuring the unique cubane-shaped [pr-4(mu(3)-oh)(4)] clusters and is a binodal 4,8-connected network with (4(16).6(12))(4(4).6(2))(2) topology. compounds 2-7 are isostructural and have 2d layered structures. compound 8 is also a 2d layer but belongs to different structural types. the luminescence behavior of compound eu(5) shows that the pi-rich aromatic organic ligands efficiently transfer the absorbed light energy to the eu(iii) ions, thus enhancing the overall luminescent properties of compound eu(5). the magnetic properties of all compounds except for the diamagnetic la(2) compound have been investigated. in addition, elemental analysis, ir spectra, and thermogravimetric analysis of these compounds are also described.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000300466300051
公开日期2013-06-08
源URL[http://ir.ciac.jl.cn/handle/322003/48312]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Liu QY,Wang WF,Wang YL,et al. Diversity of Lanthanide(III)-Organic Extended Frameworks with a 4,8-Disulfonyl-2,6-naphthalenedicarboxylic Acid Ligand: Syntheses, Structures, and Magnetic and Luminescent Properties[J]. inorganic chemistry,2012,51(4):2381-2392.
APA Liu QY,Wang WF,Wang YL,Shan ZM,Wang MS,&Tang JK.(2012).Diversity of Lanthanide(III)-Organic Extended Frameworks with a 4,8-Disulfonyl-2,6-naphthalenedicarboxylic Acid Ligand: Syntheses, Structures, and Magnetic and Luminescent Properties.inorganic chemistry,51(4),2381-2392.
MLA Liu QY,et al."Diversity of Lanthanide(III)-Organic Extended Frameworks with a 4,8-Disulfonyl-2,6-naphthalenedicarboxylic Acid Ligand: Syntheses, Structures, and Magnetic and Luminescent Properties".inorganic chemistry 51.4(2012):2381-2392.

入库方式: OAI收割

来源:长春应用化学研究所

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