Combining Coordination Modulation with Acid-Base Adjustment for the Control over Size of Metal-Organic Frameworks
文献类型：期刊论文
| 作者 | Guo HL ; Zhu YZ ; Wang S ; Su SQ ; Zhou L ; Zhang HJ |
| 刊名 | chemistry of materials
 |
| 出版日期 | 2012 |
| 卷号 | 24期号:3页码:444-450 |
| 关键词 | ZEOLITIC IMIDAZOLATE FRAMEWORK LIGHT-SCATTERING CRYSTAL-GROWTH POROUS SOLIDS THIN-FILMS NANOCRYSTALS POLYMERS TEMPERATURE COMPLEXES NANO |
| ISSN号 | 0897-4756 |
| 通讯作者 | zhang hj |
| 中文摘要 | precise control over size and morphology of metal organic frameworks (mofs) is challenging but important for extending these hybrid materials to many more advanced applications, in particular for nanotechnology and device integration. through studying parameters for the fabrication of nanosized dy(btc)(h2o) mof crystals using sodium acetate as the modulator, this paper discloses two essential parameters for miniaturizing the size of mof crystals to the nanometer scale. one is the proper acid base environment of the reaction medium which governs deprotonation of the organic linker, and, hence, the nucleation process. the other is the use of capping groups capable of inhibiting crystallites from growing. combining these two parameters makes it possible to control the size and change the morphology of dy(btc)(h2o) crystals. a mechanism based on coordination modulation together with ph adjustment is proposed for the growth of nanosized mof crystals. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000300129400005 |
| 公开日期 | 2013-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48329]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Guo HL,Zhu YZ,Wang S,et al. Combining Coordination Modulation with Acid-Base Adjustment for the Control over Size of Metal-Organic Frameworks[J]. chemistry of materials,2012,24(3):444-450. |
| APA | Guo HL,Zhu YZ,Wang S,Su SQ,Zhou L,&Zhang HJ.(2012).Combining Coordination Modulation with Acid-Base Adjustment for the Control over Size of Metal-Organic Frameworks.chemistry of materials,24(3),444-450. |
| MLA | Guo HL,et al."Combining Coordination Modulation with Acid-Base Adjustment for the Control over Size of Metal-Organic Frameworks".chemistry of materials 24.3(2012):444-450. |
入库方式： OAI收割
来源：长春应用化学研究所
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