Synthesis of Diverse Well-Defined Functional Polymers Based on Hydrozirconation and Subsequent Anti-Markovnikov Halogenation of 1,2-Polybutadiene
文献类型：期刊论文
| 作者 | Zheng J ; Liu F ; Lin YC ; Zhang ZJ ; Zhang GC ; Wang L ; Liu Y ; Tang T |
| 刊名 | macromolecules
 |
| 出版日期 | 2012 |
| 卷号 | 45期号:3页码:1190-1197 |
| 关键词 | LIVING ANIONIC-POLYMERIZATION CHEMICAL-MODIFICATION BLOCK-COPOLYMERS RADICAL-ADDITION POLYBUTADIENES POLYPROPYLENE SUBSTITUTION DERIVATIVES COMPLEXES |
| ISSN号 | 0024-9297 |
| 通讯作者 | tang t |
| 中文摘要 | for the first time, hydrozirconation and halogenolysis of 1,2-polybutadiene (1,2-pbd, by living anionic polymerization) were studied to synthesize reactive poly-halohydrocarbons, which provide a platform for preparing well-defined functional polymers via macromolecular substitution. hrirozirconation and halogenolysis afforded quite convenience for anti-markovnikov hydrohalogenation of 1,2-pbd with controllable degree of functionalization. diverse functional polymers and branched polymers were synthesized after macromolecular substitution reaction with a broad range of commercially available nucleophiles (amines, phenols, alcohols, carbanions, carboxylates, and azide) or macromolecular nucleophiles. nmr and gpc characterizations confirmed high conversion in substitution reaction and narrow molecular weight distribution of the resultant functional polymers, respectively. the methodology utilizing schwartz's reagent for hydrozirconation of macromolecules could greatly facilitate the modification of vinyl groups containing polymers with high efficiency. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000300124200007 |
| 公开日期 | 2013-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48330]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zheng J,Liu F,Lin YC,et al. Synthesis of Diverse Well-Defined Functional Polymers Based on Hydrozirconation and Subsequent Anti-Markovnikov Halogenation of 1,2-Polybutadiene[J]. macromolecules,2012,45(3):1190-1197. |
| APA | Zheng J.,Liu F.,Lin YC.,Zhang ZJ.,Zhang GC.,...&Tang T.(2012).Synthesis of Diverse Well-Defined Functional Polymers Based on Hydrozirconation and Subsequent Anti-Markovnikov Halogenation of 1,2-Polybutadiene.macromolecules,45(3),1190-1197. |
| MLA | Zheng J,et al."Synthesis of Diverse Well-Defined Functional Polymers Based on Hydrozirconation and Subsequent Anti-Markovnikov Halogenation of 1,2-Polybutadiene".macromolecules 45.3(2012):1190-1197. |
入库方式： OAI收割
来源：长春应用化学研究所
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