Solvated Crystals Based on [6,6]-Phenyl-C-61-butyric Acid Methyl Ester (PCBM) with the Hexagonal Structure and Their Phase Transformation
文献类型：期刊论文
| 作者 | Zheng LD ; Han YC |
| 刊名 | journal of physical chemistry b
 |
| 出版日期 | 2012 |
| 卷号 | 116期号:5页码:1598-1604 |
| 关键词 | FULLERENE C-60 SOLAR-CELLS METHANOFULLERENE ORGANIZATION TRANSISTORS MORPHOLOGY NANOSHEETS SOLVENT RODS C60 |
| ISSN号 | 1520-6106 |
| 通讯作者 | han yc |
| 中文摘要 | this work focuses on the structural exploration of micro-sized crystals based on a well-known methanofullerene, [6,6]-phenyl-c-61-butyric acid methyl ester (pcbm). we have succeeded in producing pcbm crystals with the hexagonal symmetry through the liquid liquid interfacial precipitation (llip) method. we found that smaller but more regular pcbm crystals tend to form in the oversaturated pcbm solutions with solvents of lower solubility for pcbm, such as tetrahydrofuran (thf) and 1,4-dioxane. the structure of the produced crystals also shows a dependence on the solvents, which can be attributed to the incorporation of different solvent molecules into pcbm crystals. under thermal annealing, for the first time, we have observed a crystalline to crystalline phase transformation of these hexagonal pcbm crystals. along with the phase transformation, the morphology of the crystals has also been transformed from the hexagon to long needles. in addition, the needlelike crystals arrange themselves with a relative angle of 60 degrees to each other, which implies an intrinsic structural correlation between needlelilce and hexagonal crystals. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000299985200015 |
| 公开日期 | 2013-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48333]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zheng LD,Han YC. Solvated Crystals Based on [6,6]-Phenyl-C-61-butyric Acid Methyl Ester (PCBM) with the Hexagonal Structure and Their Phase Transformation[J]. journal of physical chemistry b,2012,116(5):1598-1604. |
| APA | Zheng LD,&Han YC.(2012).Solvated Crystals Based on [6,6]-Phenyl-C-61-butyric Acid Methyl Ester (PCBM) with the Hexagonal Structure and Their Phase Transformation.journal of physical chemistry b,116(5),1598-1604. |
| MLA | Zheng LD,et al."Solvated Crystals Based on [6,6]-Phenyl-C-61-butyric Acid Methyl Ester (PCBM) with the Hexagonal Structure and Their Phase Transformation".journal of physical chemistry b 116.5(2012):1598-1604. |
入库方式： OAI收割
来源：长春应用化学研究所
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