Facile Synthesis of Poly(ether carbonate)s via Copolymerization of CO2 and Propylene Oxide Under Combinatorial Catalyst of Rare Earth Ternary Complex and Double Metal Cyanide Complex
文献类型：期刊论文
| 作者 | Dong YL ; Wang XH ; Zhao XJ ; Wang FS |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2012 |
| 卷号 | 50期号:2页码:362-370 |
| 关键词 | ALDIMINE ZINC-COMPLEXES COBALT-SALEN COMPLEXES ALTERNATING COPOLYMERIZATION POLY(PROPYLENE CARBONATE) COORDINATION CATALYST CO2/EPOXIDE COPOLYMERIZATION MECHANISTIC ASPECTS CYCLOHEXENE OXIDE MOLECULAR-WEIGHT MILD CONDITIONS |
| ISSN号 | 0887-624x |
| 通讯作者 | wang xh |
| 中文摘要 | poly(ether carbonate)s (ppcs) with carbonate unit (cu) content ranging from 57.8 to 97.1% and number average molecular weight (m-n) around 100 kg/mol were conveniently prepared via copolymerization of co2 and propylene oxide under combinatorial catalyst of rare earth ternary (ret) complex and double metal cyanide (dmc) complex. enhancement of catalytic activity and reduction of propylene carbonate byproduct were realized due to synergetic effect of the two metal catalysts, where dmc can be activated in the presence of ret. solubility fractionation confirmed that the obtained ppcs were copolymers, not physical blends of each polymer. thermal performances of the ppcs were closely related to their cu content, their glass transition temperatures (t-g) were tunable in the range of 6.7-36.3 degrees c, which decreased with decreasing cu content, while their thermal stabilities were enhanced significantly, an increase of 50.5 degrees c in 50% weight loss temperature was observed when cu content decreased from 97.1 to 57.8%. both shear storage modulus and complex viscosity increased with increasing cu content, which became more obvious at lower frequency, featuring well with the cu content in the ppcs. (c) 2011 wiley periodicals, inc. j polym sci part a: polym chem 50: 362-370, 2012 |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000298479300018 |
| 公开日期 | 2013-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48392]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Dong YL,Wang XH,Zhao XJ,et al. Facile Synthesis of Poly(ether carbonate)s via Copolymerization of CO2 and Propylene Oxide Under Combinatorial Catalyst of Rare Earth Ternary Complex and Double Metal Cyanide Complex[J]. journal of polymer science part a-polymer chemistry,2012,50(2):362-370. |
| APA | Dong YL,Wang XH,Zhao XJ,&Wang FS.(2012).Facile Synthesis of Poly(ether carbonate)s via Copolymerization of CO2 and Propylene Oxide Under Combinatorial Catalyst of Rare Earth Ternary Complex and Double Metal Cyanide Complex.journal of polymer science part a-polymer chemistry,50(2),362-370. |
| MLA | Dong YL,et al."Facile Synthesis of Poly(ether carbonate)s via Copolymerization of CO2 and Propylene Oxide Under Combinatorial Catalyst of Rare Earth Ternary Complex and Double Metal Cyanide Complex".journal of polymer science part a-polymer chemistry 50.2(2012):362-370. |
入库方式： OAI收割
来源：长春应用化学研究所
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