Solution reaction design: electroaccepting and electrodonating powers of ions in solution
文献类型：期刊论文
| 作者 | Li KY ; Li M ; Xue DF |
| 刊名 | nanoscale research letters
 |
| 出版日期 | 2012 |
| 卷号 | 7页码:文献号:6 |
| 关键词 | ELECTROPHILICITY INDEX IONIZATION-POTENTIALS FREE-ENERGY COMPLEXES MODEL |
| ISSN号 | 1931-7573 |
| 通讯作者 | xue df |
| 中文摘要 | by considering a first-order variation in electroaccepting and electrodonating powers,omega(+/-), induced by a change from gas to aqueous solution phase, the solvent effect on omega(+/-) for charged ions is examined. the expression of electroaccepting and electrodonating powers in the solution phase, omega(+/-)(s), is obtained through establishing the quantitative relationship between the change of the omega(+/-) due to the solvation and the hydration free energy. it is shown that cations are poorer electron acceptors and anions are poorer electron donors in solution compared to those in gas phase. we have proven that the scaled aqueous electroaccepting power, omega(+/-)(s), of cations can act as a good descriptor of the reduction reaction, which is expected to be applied in the design of solution reactions. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000300302800001 |
| 公开日期 | 2013-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48402]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li KY,Li M,Xue DF. Solution reaction design: electroaccepting and electrodonating powers of ions in solution[J]. nanoscale research letters,2012,7:文献号:6. |
| APA | Li KY,Li M,&Xue DF.(2012).Solution reaction design: electroaccepting and electrodonating powers of ions in solution.nanoscale research letters,7,文献号:6. |
| MLA | Li KY,et al."Solution reaction design: electroaccepting and electrodonating powers of ions in solution".nanoscale research letters 7(2012):文献号:6. |
入库方式： OAI收割
来源：长春应用化学研究所
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