A series of POM/Ag-based hybrids: distinct forms and assembly of [AgxLy] complexes through combinational effects of POM and isomeric ligands
文献类型：期刊论文
| 作者 | Zhu M ; Su SQ ; Song XZ ; Hao ZM ; Song SY ; Zhang HJ |
| 刊名 | crystengcomm
 |
| 出版日期 | 2012 |
| 卷号 | 14期号:20页码:6452-6461 |
| 关键词 | AG-I INTERACTIONS BUILDING-BLOCKS SUPRAMOLECULAR SYNTHONS OCTAMOLYBDATE CLUSTERS COORDINATION POLYMER POLYOXOMETALATE FRAMEWORK PH UNITS ACETYLENEDIIDE |
| ISSN号 | 1466-8033 |
| 通讯作者 | zhang hj |
| 中文摘要 | five pom/ag-based hybrids were obtained under hydrothermal conditions: (agla)(2)[ag2l2a(siw12o40)](1), [(aglb)(2)-ag2l2b][(siw12o40)] (2) na-2[agla(hla)](2)[ag5l4a(h2o)(2)][h(p2w18o62)(2)]center dot 21.6h(2)o (3), [ag5l5b][k2(oh)p2w18o62]center dot h2o (4) and [ag2l2a][hpw12o40]center dot 7.5h(2)o (5) (l-a = 1,2-bis(imidazol-1-ylmethyl)benzene; l-b = 1,3-bis(imidazol-1-ylmethyl)benzene). it is likely that the forms and assembly of [agxly]complexes are crucial to the eventual structures, which are quite dependent on the pom and isomeric ligands in combination. compound 1 shows a "s"-like chain structure with [(agla)(2)](n)(2n+) templates, while compound 2 features a unique 2d layer constructed by polypseudo-rotoxane motifs and infinite ag chains. compound 3 exhibits a 2d layer consisting of {dawson-ag-5} double chain and [agl2a] complexes. compound 4 possesses a 3d poly-threading framework containing {pom-k} chains and interdigitated metal-organic layers. compound 5 is a 1d chain, formed by keggin anions and [ag2l2a]circles. further, the luminescent and electrochemical properties of 1-5 are also investigated. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000308827100022 |
| 公开日期 | 2013-06-30 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48452]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhu M,Su SQ,Song XZ,et al. A series of POM/Ag-based hybrids: distinct forms and assembly of [AgxLy] complexes through combinational effects of POM and isomeric ligands[J]. crystengcomm,2012,14(20):6452-6461. |
| APA | Zhu M,Su SQ,Song XZ,Hao ZM,Song SY,&Zhang HJ.(2012).A series of POM/Ag-based hybrids: distinct forms and assembly of [AgxLy] complexes through combinational effects of POM and isomeric ligands.crystengcomm,14(20),6452-6461. |
| MLA | Zhu M,et al."A series of POM/Ag-based hybrids: distinct forms and assembly of [AgxLy] complexes through combinational effects of POM and isomeric ligands".crystengcomm 14.20(2012):6452-6461. |
入库方式： OAI收割
来源：长春应用化学研究所
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