One-pot depolymerization of cellulose into glucose and levulinic acid by heteropolyacid ionic liquid catalysis
文献类型:期刊论文
作者 | Sun Z ; Cheng MX ; Li HC ; Shi T ; Yuan MJ ; Wang XH ; Jiang ZJ |
刊名 | rsc advances
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出版日期 | 2012 |
卷号 | 2期号:24页码:9058-9065 |
关键词 | SOLID ACID CLEAN PRODUCTION HYDROLYSIS POLYSACCHARIDES CONVERSION BIOMASS |
ISSN号 | 2046-2069 |
通讯作者 | sun z |
中文摘要 | a series of heteropolyacid (hpa) ionic liquids [c4h6n2(ch2)(3)so3h](3-n)hnpw12o40 ([mimpsh](n)h3-npw12o40, n = 1, 2 3, abbreviated as [mimpsh](n)h3-npw) was used to catalyze one-pot depolymerization of cellulose into glucose. their performances were much better than those of the previously reported hpas, such as h3pw12o40, cs2.5h0.5pw12o40. besides cellulose, the hpa ionic liquids were able to catalyze the conversion of sucrose and starch into glucose. in addition, one-pot synthesis of levulinic acid (la) directly from cellulose was realized using these hpa ionic liquid catalysts in a water-methyl isobutyl ketone (mibk) biphasic system. the separation of the products and catalysts was easy, and the retrieved [mimpsh](n)h3-npw could be repeatedly used without appreciable loss of performance. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000308824600028 |
公开日期 | 2013-06-30 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48474] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Sun Z,Cheng MX,Li HC,et al. One-pot depolymerization of cellulose into glucose and levulinic acid by heteropolyacid ionic liquid catalysis[J]. rsc advances,2012,2(24):9058-9065. |
APA | Sun Z.,Cheng MX.,Li HC.,Shi T.,Yuan MJ.,...&Jiang ZJ.(2012).One-pot depolymerization of cellulose into glucose and levulinic acid by heteropolyacid ionic liquid catalysis.rsc advances,2(24),9058-9065. |
MLA | Sun Z,et al."One-pot depolymerization of cellulose into glucose and levulinic acid by heteropolyacid ionic liquid catalysis".rsc advances 2.24(2012):9058-9065. |
入库方式: OAI收割
来源:长春应用化学研究所
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