Color tuning via energy transfer in Sr3In(PO4)(3):Ce3+/Tb3+/Mn2+ phosphors
文献类型：期刊论文
| 作者 | Geng DL ; Li GG ; Shang MM ; Yang DM ; Zhang Y ; Cheng ZY ; Lin J |
| 刊名 | journal of materials chemistry
 |
| 出版日期 | 2012 |
| 卷号 | 22期号:28页码:14262-14271 |
| 关键词 | FIELD-EMISSION DISPLAYS LIGHT-EMITTING-DIODES LUMINESCENCE PROPERTIES CATHODOLUMINESCENT PROPERTIES NANOCRYSTALLINE PHOSPHORS OPTICAL-PROPERTIES TB3+ MN2+ EXCITATION GREEN |
| ISSN号 | 0959-9428 |
| 通讯作者 | lin j |
| 中文摘要 | sr3in(po4)(3) (sip):ce3+/tb3+/mn2+ phosphors have been prepared via a solid state reaction process. under uv excitation, there are three energy transfer (et) pairs in the sip host, i.e., ce3+ -> tb3+, ce3+ -> mn2+, and tb3+ -> mn2+. both of the ets from ce3+ to tb3+ and from ce3+ to mn2+ in the sip host have been demonstrated to be resonant type via a dipole-quadrupole mechanism, and the critical distance (r-c) calculated by the quenching concentration method and spectral overlap method, respectively, were investigated. by the et of ce3+ -> tb3+, ce3+ -> mn2+, and tb3+ -> mn2+ the emitting colors of the studied samples could be adjusted from blue to green, from blue to orange-red, and from green to green-yellow, respectively. more importantly, under low-voltage electron beam excitation, the cl spectra of the sip:ce3+, mn2+ samples cover the whole visible light region, resulting in a white light emission. additionally, the cl properties of sip:ce3+/tb3+/mn2+ phosphors have been investigated in detail. the results reveal that the as-prepared phosphors have good cl intensity and cie coordinate stability under electron beam bombardment. compared with the commercial green phosphor zno:zn, sip:7% ce3+, the 10% tb3+ sample has a higher cl brightness. in conclusion, tunable light with high quantum yield (68%) has been obtained in sip:ce3+/tb3+/mn2+ phosphors by utilizing the principle of energy transfer and properly selecting the activator contents under uv and electron beam excitation. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000305796300055 |
| 公开日期 | 2013-06-30 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48504]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Geng DL,Li GG,Shang MM,et al. Color tuning via energy transfer in Sr3In(PO4)(3):Ce3+/Tb3+/Mn2+ phosphors[J]. journal of materials chemistry,2012,22(28):14262-14271. |
| APA | Geng DL.,Li GG.,Shang MM.,Yang DM.,Zhang Y.,...&Lin J.(2012).Color tuning via energy transfer in Sr3In(PO4)(3):Ce3+/Tb3+/Mn2+ phosphors.journal of materials chemistry,22(28),14262-14271. |
| MLA | Geng DL,et al."Color tuning via energy transfer in Sr3In(PO4)(3):Ce3+/Tb3+/Mn2+ phosphors".journal of materials chemistry 22.28(2012):14262-14271. |
入库方式： OAI收割
来源：长春应用化学研究所
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