Polymer assisted solution-processing of rubrene spherulites via solvent vapor annealing
文献类型:期刊论文
作者 | Su YJ ; Liu JG ; Zheng LD ; Ding ZC ; Han YC |
刊名 | rsc advances
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出版日期 | 2012 |
卷号 | 2期号:13页码:5779-5788 |
关键词 | FIELD-EFFECT TRANSISTORS THIN-FILM TRANSISTORS SINGLE-CRYSTALS ORGANIC SEMICONDUCTORS PERFORMANCE TRANSPORT BLENDS GROWTH MOLECULE |
ISSN号 | 2046-2069 |
通讯作者 | su yj |
中文摘要 | in this work, solution-processing rubrene spherulites were fabricated by blending an amount of polymer into rubrene and subsequent solvent vapor annealing (sva). the content and molecular weight of the blended polymer, the annealing solvent and the solvent vapor pressure have tremendous influence on the formation of rubrene spherulites. rubrene spherulites were produced only when a polymer with a high molecular weight was blended and annealed by good solvents of rubrene with high vapor pressures, such as ch2cl2 and cs2. the sizes of the spherulites decreased with the reduction of the annealing solvent vapor pressure. the rubrene spherulites adopted a triclinic system with c-axis perpendicular to the substrate. the crystallizing kinetics study displayed a rather fast growth of rubrene spherulites and the crystallization of rubrene was controlled by diffusion. a competitive mechanism between the impetus of the annealing solvent vapor and the impeditive force of the polymer on the diffusion of rubrene molecules to the crystal fronts was proposed to explain the formation of rubrene spherulites. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000305274600048 |
公开日期 | 2013-06-30 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48533] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Su YJ,Liu JG,Zheng LD,et al. Polymer assisted solution-processing of rubrene spherulites via solvent vapor annealing[J]. rsc advances,2012,2(13):5779-5788. |
APA | Su YJ,Liu JG,Zheng LD,Ding ZC,&Han YC.(2012).Polymer assisted solution-processing of rubrene spherulites via solvent vapor annealing.rsc advances,2(13),5779-5788. |
MLA | Su YJ,et al."Polymer assisted solution-processing of rubrene spherulites via solvent vapor annealing".rsc advances 2.13(2012):5779-5788. |
入库方式: OAI收割
来源:长春应用化学研究所
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