The combination of a polymer-carbon composite electrode with a high-absorptivity ruthenium dye achieves an efficient dye-sensitized solar cell based on a thiolate-disulfide redox couple
文献类型：期刊论文
| 作者 | Zhang J ; Long HJ ; Miralles SG ; Bisquert J ; Fabregat-Santiago F ; Zhang M |
| 刊名 | physical chemistry chemical physics
 |
| 出版日期 | 2012 |
| 卷号 | 14期号:19页码:7131-7136 |
| 关键词 | NANOCRYSTALLINE TITANIUM-DIOXIDE COUNTER ELECTRODES POLYPYRIDINE COMPLEXES TRANSFER MEDIATORS OXYGEN REDUCTION IONIC LIQUID LOW-COST PERFORMANCE COBALT TIO2 |
| ISSN号 | 1463-9076 |
| 通讯作者 | fabregat-santiago f |
| 中文摘要 | to overcome the intrinsic shortcomings of the traditional iodide-triiodide redox couple and pursue a further performance improvement, intense efforts have been made to exploit alternative redox shuttles in dye-sensitized solar cells (dscs). herein, we report an energetic and kinetic view of dscs when the iodine electrolyte is substituted with its thiolate counterpart and identify that a conventional platinum counter electrode presents low catalytic activity for the thiolate electrolyte, featuring a high charge transfer resistance found at the platinized fluorine-doped tin oxide (fto). we employ conductive carbon black with several polymers to fabricate highly active composite catalysts for thiolate regeneration. the use of a highly active conductive carbon black and polymerized 3,4-ethylenedioxythiophene composition as a counter electrode combined with a high-absorptivity ruthenium dye c106 sensitized titania film has generated a dsc with an organic thiolated electrolyte, exhibiting an overall power conversion efficiency of 7.6% under am1.5g full sunlight. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000303251100051 |
| 公开日期 | 2013-06-30 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48573]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang J,Long HJ,Miralles SG,et al. The combination of a polymer-carbon composite electrode with a high-absorptivity ruthenium dye achieves an efficient dye-sensitized solar cell based on a thiolate-disulfide redox couple[J]. physical chemistry chemical physics,2012,14(19):7131-7136. |
| APA | Zhang J,Long HJ,Miralles SG,Bisquert J,Fabregat-Santiago F,&Zhang M.(2012).The combination of a polymer-carbon composite electrode with a high-absorptivity ruthenium dye achieves an efficient dye-sensitized solar cell based on a thiolate-disulfide redox couple.physical chemistry chemical physics,14(19),7131-7136. |
| MLA | Zhang J,et al."The combination of a polymer-carbon composite electrode with a high-absorptivity ruthenium dye achieves an efficient dye-sensitized solar cell based on a thiolate-disulfide redox couple".physical chemistry chemical physics 14.19(2012):7131-7136. |
入库方式： OAI收割
来源：长春应用化学研究所
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