Ag nanoparticles decorated polyaniline nanofibers: synthesis, characterization, and applications toward catalytic reduction of 4-nitrophenol and electrochemical detection of H2O2 and glucose
文献类型:期刊论文
作者 | Chang GH ; Luo YL ; Lu WB ; Qin XY ; Asiri AM ; Al-Youbi AO ; Sun XP |
刊名 | catalysis science & technology
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出版日期 | 2012 |
卷号 | 2期号:4页码:800-806 |
关键词 | ELECTROCATALYTIC ACTIVITY ULTRASONIC IRRADIATION FACILE SYNTHESIS GRAPHENE OXIDE P-AMINOPHENOL NANOSTRUCTURES NANOTUBES OXIDATION ELECTROPOLYMERIZATION ELECTRODEPOSITION |
ISSN号 | 2044-4753 |
通讯作者 | chang gh |
中文摘要 | polyaniline nanofibers (paninfs) have been facilely prepared by electrochemical polymerization of aniline monomers in acidic aqueous media without using any templates and surfactants. the subsequent treatment of such nanofibers with a agno3 aqueous solution leads to in situ chemical reduction of ag+ on them to form ag nanoparticles decorated paninfs (agnps/paninfs) nanocomposites. we investigated the catalytic activity and electrochemical properties of these nanocomposites. it is found that such nanocomposites exhibit excellent catalytic activity toward reduction of 4-nitrophenol to 4-aminophenol by nabh4 and exhibit remarkable catalytic performance for h2o2 reduction. the enzymeless h2o2 sensor constructed using the nanocomposites shows a fast amperometric response time of less than 3 s. the linear range and detection limit are estimated to be from 0.1 mm to 60 mm (r = 0.998) and 1.7 mu m at a signal-to-noise ratio of 3, respectively. we have fabricated a glucose biosensor by immobilizing glucose oxidase into the agnps/paninfs-modified glassy carbon electrode for glucose detection. this sensor exhibits good response to glucose. the linear response range is estimated to be from 1 mm to 12 mm (r = 0.997) at -0.58 v. the detection limit is estimated to be 0.25 mm at a signal-to-noise ratio of 3. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000302062900020 |
公开日期 | 2013-06-30 |
源URL | [http://ir.ciac.jl.cn/handle/322003/48605] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Chang GH,Luo YL,Lu WB,et al. Ag nanoparticles decorated polyaniline nanofibers: synthesis, characterization, and applications toward catalytic reduction of 4-nitrophenol and electrochemical detection of H2O2 and glucose[J]. catalysis science & technology,2012,2(4):800-806. |
APA | Chang GH.,Luo YL.,Lu WB.,Qin XY.,Asiri AM.,...&Sun XP.(2012).Ag nanoparticles decorated polyaniline nanofibers: synthesis, characterization, and applications toward catalytic reduction of 4-nitrophenol and electrochemical detection of H2O2 and glucose.catalysis science & technology,2(4),800-806. |
MLA | Chang GH,et al."Ag nanoparticles decorated polyaniline nanofibers: synthesis, characterization, and applications toward catalytic reduction of 4-nitrophenol and electrochemical detection of H2O2 and glucose".catalysis science & technology 2.4(2012):800-806. |
入库方式: OAI收割
来源:长春应用化学研究所
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