Steric hindrances create a discrete linear Dy-4 complex exhibiting SMM behaviour
文献类型：期刊论文
| 作者 | Lin SY ; Zhao L ; Ke HS ; Guo YN ; Tang JK ; Guo Y ; Dou JM |
| 刊名 | dalton transactions
 |
| 出版日期 | 2012 |
| 卷号 | 41期号:11页码:3248-3252 |
| 关键词 | SINGLE-MOLECULE-MAGNET LANTHANIDE COMPLEXES SLOW RELAXATION ANISOTROPIC BARRIER ION LN TRIANGLES CLUSTER LIGAND SERIES MAGNETIZATION |
| ISSN号 | 1477-9226 |
| 通讯作者 | tang jk |
| 中文摘要 | two linear tetranuclear lanthanide complexes of general formula [ln(4)(l)(2)(c6h5coo)(12)(meoh)(4)], where hl = 2,6-bis((furan-2-ylmethylimino) methyl)-4-methylphenol, (scheme 1) and ln(iii) = dy-iii (1) and gd-iii (2), have been synthesized and characterized. the crystal structural analysis demonstrates that two schiff-base ligands inhibit the growth of benzoate bridged 1d chains, leading to the isolation of discrete tetranuclear complexes due to their steric hindrances. every ln(iii) ion is coordinated by eight donor atoms in a distorted bicapped trigonal-prismatic arrangement. alternating current (ac) susceptibility measurements of complex 1 reveal a frequency-and temperature-dependent out-of-phase signal under zero dc field, typical of single-molecule magnet (smm) behaviour with an anisotropic barrier delta(eff) = 17.2 k. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000300737900021 |
| 公开日期 | 2013-06-30 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48627]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lin SY,Zhao L,Ke HS,et al. Steric hindrances create a discrete linear Dy-4 complex exhibiting SMM behaviour[J]. dalton transactions,2012,41(11):3248-3252. |
| APA | Lin SY.,Zhao L.,Ke HS.,Guo YN.,Tang JK.,...&Dou JM.(2012).Steric hindrances create a discrete linear Dy-4 complex exhibiting SMM behaviour.dalton transactions,41(11),3248-3252. |
| MLA | Lin SY,et al."Steric hindrances create a discrete linear Dy-4 complex exhibiting SMM behaviour".dalton transactions 41.11(2012):3248-3252. |
入库方式： OAI收割
来源：长春应用化学研究所
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