Formation of Chiral alpha-Monofluorinated-beta-amino Esters through Organocatalytic Asymmetric Reduction of alpha-Fluoro-beta-enamino Esters by Trichlorosilane
文献类型：期刊论文
| 作者 | Zhang Peng ; Wang Chao ; Zhou Li ; Sun Jian |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 30期号:11页码:2636-2640 |
| 关键词 | asymmetric reduction sulfinyl urea alpha-fluorinated-beta-amino ester stereoselectivity |
| ISSN号 | 1001-604X |
| 产权排序 | 1 |
| 通讯作者 | Wang, C (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Sichuan, Peoples R China. |
| 英文摘要 | A concise method was developed to prepare chiral alpha-monofluorinated-beta-amino esters through N-sulfinyl urea catalyzed asymmetric hydrosilylation of alpha-fluoro-beta-enamino esters, which affords high yields, good to high diastereoselectivities (up to>99/1), and moderate to good enantioselectivities (up to 83% ee). |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China [20972151, 21272227, 91013006] |
| 语种 | 英语 |
| WOS记录号 | WOS:000311169300008 |
| 公开日期 | 2013-07-03 |
| 源URL | [http://210.75.237.14/handle/351003/23876]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Zhang Peng,Wang Chao,Zhou Li,et al. Formation of Chiral alpha-Monofluorinated-beta-amino Esters through Organocatalytic Asymmetric Reduction of alpha-Fluoro-beta-enamino Esters by Trichlorosilane[J]. CHINESE JOURNAL OF CHEMISTRY,2012,30(11):2636-2640. |
| APA | Zhang Peng,Wang Chao,Zhou Li,&Sun Jian.(2012).Formation of Chiral alpha-Monofluorinated-beta-amino Esters through Organocatalytic Asymmetric Reduction of alpha-Fluoro-beta-enamino Esters by Trichlorosilane.CHINESE JOURNAL OF CHEMISTRY,30(11),2636-2640. |
| MLA | Zhang Peng,et al."Formation of Chiral alpha-Monofluorinated-beta-amino Esters through Organocatalytic Asymmetric Reduction of alpha-Fluoro-beta-enamino Esters by Trichlorosilane".CHINESE JOURNAL OF CHEMISTRY 30.11(2012):2636-2640. |
入库方式： OAI收割
来源：成都生物研究所
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