Synthesis of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed enantioselective hydrogenation beta-ketoesters
文献类型：期刊论文
| 作者 | Wan XB(万小兵) ; Sun YH(孙延晖) ; Luo YF(罗云飞) ; Li D(李到) ; Zhang ZG(张兆国) |
| 刊名 | J. Org. Chem.
 |
| 出版日期 | 2005 |
| 卷号 | 70期号:3页码:1070-1072 |
| ISSN号 | 0022-3263 |
| 其他题名 | Synthesis of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed enantioselective hydrogenation beta-ketoesters |
| 通讯作者 | 张兆国 |
| 英文摘要 | The synthesis and resolution of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed asymmetric hydrogenation reaction of beta-ketoesters are reported. Up to 99.5% ee was achieved. Under solvent-free reaction conditions, acetoacetates could be reduced with good enantioselectivity and high efficiency; a TON of 20 000 was obtained within 3.5 h. The results obtained were comparable to those when SEGPhos was applied. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/jo048466d |
| 语种 | 英语 |
| WOS记录号 | WOS:000226777100045 |
| 公开日期 | 2013-08-14 |
| 源URL | [http://202.127.28.38/handle/331003/27619]  |
| 专题 | 上海有机化学研究所_上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Wan XB,Sun YH,Luo YF,et al. Synthesis of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed enantioselective hydrogenation beta-ketoesters[J]. J. Org. Chem.,2005,70(3):1070-1072. |
| APA | 万小兵,孙延晖,罗云飞,李到,&张兆国.(2005).Synthesis of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed enantioselective hydrogenation beta-ketoesters.J. Org. Chem.,70(3),1070-1072. |
| MLA | 万小兵,et al."Synthesis of a bulky and electron-rich derivative of SEGPhos and its application in Ru-catalyzed enantioselective hydrogenation beta-ketoesters".J. Org. Chem. 70.3(2005):1070-1072. |
入库方式： OAI收割
来源：上海有机化学研究所
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