A non-cross-linked soluble polystyrene-supported ruthenium catalyst for carbenoid transfer reactions
文献类型：期刊论文
| 作者 | CHI MATTHEW KWOKWAI ; YU WINGYIU ; SO MANHO ; ZHOU CONGYING ; Deng QH(邓清海) ; Zhi ZM(支志明) |
| 刊名 | Chem.-Asian J.
 |
| 出版日期 | 2008 |
| 卷号 | 3期号:8-9页码:1256-1265 |
| ISSN号 | 1861-4728 |
| 其他题名 | A non-cross-linked soluble polystyrene-supported ruthenium catalyst for carbenoid transfer reactions |
| 通讯作者 | 支志明 |
| 英文摘要 | Ruthenium nanoparticles supported on non-cross-linked soluble polystyrene were prepared by reacting [RuCl2(C6H5CO2Et)](2) with polystyrene in open air. They effectively catalyze intra- and intermolecular carbenoid insertion into C-H and N-H bonds, alkene cyclopropanation, and ammonium ylide/[2,3]-sigmatropic rearrangement reactions. This supported ruthenium catalyst is much more reactive than [RuCl2(p-cymene)](2) and [Ru(Por)CO] for catalytic intermolecular carbenoid C-H bond insertion into saturated alkanes. By using alpha-diazoacetamide as a substrate for intramolecular carbenoid C-H insertion, the supported ruthenium catalyst can be recovered and reused for ten successive iterations without significant loss of activity. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/asia.200800144 |
| 语种 | 英语 |
| WOS记录号 | WOS:000259119400005 |
| 公开日期 | 2013-08-14 |
| 源URL | [http://202.127.28.38/handle/331003/27705]  |
| 专题 | 上海有机化学研究所_上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | CHI MATTHEW KWOKWAI,YU WINGYIU,SO MANHO,et al. A non-cross-linked soluble polystyrene-supported ruthenium catalyst for carbenoid transfer reactions[J]. Chem.-Asian J.,2008,3(8-9):1256-1265. |
| APA | CHI MATTHEW KWOKWAI,YU WINGYIU,SO MANHO,ZHOU CONGYING,邓清海,&支志明.(2008).A non-cross-linked soluble polystyrene-supported ruthenium catalyst for carbenoid transfer reactions.Chem.-Asian J.,3(8-9),1256-1265. |
| MLA | CHI MATTHEW KWOKWAI,et al."A non-cross-linked soluble polystyrene-supported ruthenium catalyst for carbenoid transfer reactions".Chem.-Asian J. 3.8-9(2008):1256-1265. |
入库方式： OAI收割
来源：上海有机化学研究所
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