Thermogravimetry study of the pyrolytic characteristics and kinetics of macro-algae Macrocystis pyrifera residue
文献类型:期刊论文
作者 | Zhao, Hui1,2; Yan, Huaxiao1,2; Dong, Shuangshuang1,2; Zhang, Yan1,2; Sun, Binbin1,2; Zhang, Congwang1,2; Ai, Yanxiang1,2; Chen, Biaoqi1,2; Liu, Qi1,2; Sui, Tongtong1,2 |
刊名 | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
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出版日期 | 2013-03-01 |
卷号 | 111期号:3页码:1685-1690 |
关键词 | Biomass Macro-algae Macrocystis pyrifera Residue Pyrolysis Kinetics TG-DTG-DSC |
ISSN号 | 1388-6150 |
产权排序 | [Zhao, Hui; Yan, Huaxiao; Dong, Shuangshuang; Zhang, Yan; Sun, Binbin; Zhang, Congwang; Ai, Yanxiang; Chen, Biaoqi; Liu, Qi; Sui, Tongtong] Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Qingdao 266590, Peoples R China; [Zhao, Hui; Yan, Huaxiao; Dong, Shuangshuang; Zhang, Yan; Sun, Binbin; Zhang, Congwang; Ai, Yanxiang; Chen, Biaoqi; Liu, Qi; Sui, Tongtong] Shandong Prov Key Lab Low Carbon Energy Chem Engn, Qingdao 266590, Peoples R China; [Qin, Song] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Bioresources Lab, Yantai 264003, Shandong, Peoples R China |
通讯作者 | Zhao, H (reprint author), Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Qingdao 266590, Peoples R China. zhsdust@126.com |
中文摘要 | Macrocystis pyrifera is one important marine macro-algae, while its residues produced by industrial alginate extraction is a hot potato. To figure out whether its residue is suitable for pyrolysis for biofuel, the pyrolytic characteristics and kinetics of macro-algae M. pyrifera residue was investigated using thermogravimetric method from 50 to 800 A degrees C in an inert argon atmosphere at different heating rates of 5, 10, 20, and 30 A degrees C min(-1). The activation energy and pre-exponential factor was calculated by Flynn-Wall-Ozawa, Kissinger-Akahira-Sunose, and Popescu methods, and the kinetic mechanism was deduced by Popescu method. The results showed that the primary devolatilization stage of M. pyrifera residue can be described by Jander function . The average activation energy of M. pyrifera residue was 222.4 kJ mol(-1). The results suggested that the experimental results and kinetic parameters provided useful information for the design of pyrolytic processing system using M. pyrifera residue as feedstock. |
英文摘要 | Macrocystis pyrifera is one important marine macro-algae, while its residues produced by industrial alginate extraction is a hot potato. To figure out whether its residue is suitable for pyrolysis for biofuel, the pyrolytic characteristics and kinetics of macro-algae M. pyrifera residue was investigated using thermogravimetric method from 50 to 800 A degrees C in an inert argon atmosphere at different heating rates of 5, 10, 20, and 30 A degrees C min(-1). The activation energy and pre-exponential factor was calculated by Flynn-Wall-Ozawa, Kissinger-Akahira-Sunose, and Popescu methods, and the kinetic mechanism was deduced by Popescu method. The results showed that the primary devolatilization stage of M. pyrifera residue can be described by Jander function . The average activation energy of M. pyrifera residue was 222.4 kJ mol(-1). The results suggested that the experimental results and kinetic parameters provided useful information for the design of pyrolytic processing system using M. pyrifera residue as feedstock. |
学科主题 | Chemistry, Analytical; Chemistry, Physical |
研究领域[WOS] | Chemistry |
关键词[WOS] | GIANT-KELP MACROCYSTIS ; THERMAL-ANALYSIS ; MICROALGAE ; BEHAVIOR ; ALGINATE ; ENERGY ; FOOD |
收录类别 | SCI |
资助信息 | National Natural Science Foundation of China [21076117]; CAS; Outstanding young scholar fellowship of Shandong Province [JQ200914]; State Key Laboratory of Crop Biology [2010KF06, 2011KF14]; Shandong Agricultural University; Shandong Province Higher Educational Science and Technology Program [J09LC22, J10LC15]; Key Laboratory of Experimental Marine Biology, Institute of Oceanology [Kf201016]; Key Laboratory of Marine Bio-resources Sustainable Utilization, SCSIO, Chinese Academy of Sciences [LMB101004] |
原文出处 | 10.1007/s10973-011-2102-8 |
语种 | 英语 |
WOS记录号 | WOS:000315298800006 |
公开日期 | 2013-08-14 |
源URL | [http://ir.yic.ac.cn/handle/133337/6469] ![]() |
专题 | 烟台海岸带研究所_海岸带生物学与生物资源利用所重点实验室 |
作者单位 | 1.Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Qingdao 266590, Peoples R China 2.Shandong Prov Key Lab Low Carbon Energy Chem Engn, Qingdao 266590, Peoples R China 3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Bioresources Lab, Yantai 264003, Shandong, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Hui,Yan, Huaxiao,Dong, Shuangshuang,et al. Thermogravimetry study of the pyrolytic characteristics and kinetics of macro-algae Macrocystis pyrifera residue[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2013,111(3):1685-1690. |
APA | Zhao, Hui.,Yan, Huaxiao.,Dong, Shuangshuang.,Zhang, Yan.,Sun, Binbin.,...&Qin, Song.(2013).Thermogravimetry study of the pyrolytic characteristics and kinetics of macro-algae Macrocystis pyrifera residue.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,111(3),1685-1690. |
MLA | Zhao, Hui,et al."Thermogravimetry study of the pyrolytic characteristics and kinetics of macro-algae Macrocystis pyrifera residue".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 111.3(2013):1685-1690. |
入库方式: OAI收割
来源:烟台海岸带研究所
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