Tetranuclear mixed-valence Co(II/III) and binuclear Ni(II) complexesincorporating hydroxyl-rich ligand: Syntheses, structures and magneticproperties
文献类型：期刊论文
| 作者 | Zhang, Su-Yun ; Zheng, Lina ; Chen, Wenqian ; Li, Yahong |
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2011 |
| 卷号 | 367期号:1页码:44-50 |
| 关键词 | Tetranuclear clusters Mixed-valence Coordination mode Binuclear |
| 英文摘要 | Three complexes of composition [(Co2Co2III)-Co-II(H(2)hbhpd)(2)(H(4)hbhpd)(2)(H2O)(2)]Cl-2(CH3OH)(4) (1), [(Co2Co2III)-Co-II (H(2)hbhpd)(2)(H(4)hbhpd)(2)(H2O)(2)](NO3)(2)(CH3OH)(4) (2) and [Ni-2(H(4)hbhpd)(2)(NO3)](NO3)(CH3OH)(1.5) (3) (H(5)hbhpd = 2-(2-hydroxy-benzylamino)-2-hydroxymethyl-propane-1,3-diol) have been synthesized and their structures have been characterized. Complexes 1 and 2 are mixed-valence cobalt clusters and display face-sharing monovacant dicubane structures. In the complexes 1 and 2, one of the three alkyl hydroxyl groups of H(5)hbhpd ligand is deprotonated instead of deprotonation of phenyl hydroxyl group; thus monoanionic H(4)hbhpd ligand displays novel eta(3), eta(1), eta(1), mu(3) coordination mode. Complex 3 is binuclear, and the two metal centers of 3 are bridged by two deprotonated phenyl hydroxyl oxygen atoms and iso-orthogonalized by a nitrato group in eta(1)eta(1)-O,O' coordination fashion. Variable-temperature solid-state dc magnetization studies have been performed in the temperature range 2-300 K for compounds 1 and 3. Antiferromagnetic interactions were determined for 1 and ferromagnetic couplings were found for 3. (C) 2010 Elsevier B.V. All rights reserved. Three complexes of composition [(Co2Co2III)-Co-II(H(2)hbhpd)(2)(H(4)hbhpd)(2)(H2O)(2)]Cl-2(CH3OH)(4) (1), [(Co2Co2III)-Co-II (H(2)hbhpd)(2)(H(4)hbhpd)(2)(H2O)(2)](NO3)(2)(CH3OH)(4) (2) and [Ni-2(H(4)hbhpd)(2)(NO3)](NO3)(CH3OH)(1.5) (3) (H(5)hbhpd = 2-(2-hydroxy-benzylamino)-2-hydroxymethyl-propane-1,3-diol) have been synthesized and their structures have been characterized. Complexes 1 and 2 are mixed-valence cobalt clusters and display face-sharing monovacant dicubane structures. In the complexes 1 and 2, one of the three alkyl hydroxyl groups of H(5)hbhpd ligand is deprotonated instead of deprotonation of phenyl hydroxyl group; thus monoanionic H(4)hbhpd ligand displays novel eta(3), eta(1), eta(1), mu(3) coordination mode. Complex 3 is binuclear, and the two metal centers of 3 are bridged by two deprotonated phenyl hydroxyl oxygen atoms and iso-orthogonalized by a nitrato group in eta(1)eta(1)-O,O' coordination fashion. Variable-temperature solid-state dc magnetization studies have been performed in the temperature range 2-300 K for compounds 1 and 3. Antiferromagnetic interactions were determined for 1 and ferromagnetic couplings were found for 3. (C) 2010 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-08-22 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/1884]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 推荐引用方式 GB/T 7714 | Zhang, Su-Yun,Zheng, Lina,Chen, Wenqian,et al. Tetranuclear mixed-valence Co(II/III) and binuclear Ni(II) complexesincorporating hydroxyl-rich ligand: Syntheses, structures and magneticproperties[J]. INORGANICA CHIMICA ACTA,2011,367(1):44-50. |
| APA | Zhang, Su-Yun,Zheng, Lina,Chen, Wenqian,&Li, Yahong.(2011).Tetranuclear mixed-valence Co(II/III) and binuclear Ni(II) complexesincorporating hydroxyl-rich ligand: Syntheses, structures and magneticproperties.INORGANICA CHIMICA ACTA,367(1),44-50. |
| MLA | Zhang, Su-Yun,et al."Tetranuclear mixed-valence Co(II/III) and binuclear Ni(II) complexesincorporating hydroxyl-rich ligand: Syntheses, structures and magneticproperties".INORGANICA CHIMICA ACTA 367.1(2011):44-50. |
入库方式： OAI收割
来源：青海盐湖研究所
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