Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand:Synthesis, Crystal Structure and Magnetic Property
文献类型：期刊论文
| 作者 | Zhao, Yang ; Zhang, Suyun ; Zheng, Lina ; Li, Yahong |
| 刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
 |
| 出版日期 | 2011 |
| 卷号 | 637期号:10页码:1304-1307 |
| 关键词 | 2-Pyridyloximate Tetranuclear complexes Manganese IR spectroscopy |
| 英文摘要 | A tetranuclear manganese complex of the composition {Mn(4)[(Py)C(Ph)NO](4)(CH(3)CH(2)OH)(3)(CH(3)CH(2)O)Cl(3)}center dot 2H(2)O (1) was synthesized by solvothermal reaction, and characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. X-ray analysis revealed that complex 1 contains a [Mn(4)(NO)(4)](4+) core with three Mn(II) atoms displaying distorted octahedral arrangements and one Mn(II) ion exhibiting a trigonal bipyramidal arrangement. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed antiferromagnetic Mn(II)center dot center dot center dot Mn(II) interactions. A tetranuclear manganese complex of the composition {Mn(4)[(Py)C(Ph)NO](4)(CH(3)CH(2)OH)(3)(CH(3)CH(2)O)Cl(3)}center dot 2H(2)O (1) was synthesized by solvothermal reaction, and characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. X-ray analysis revealed that complex 1 contains a [Mn(4)(NO)(4)](4+) core with three Mn(II) atoms displaying distorted octahedral arrangements and one Mn(II) ion exhibiting a trigonal bipyramidal arrangement. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed antiferromagnetic Mn(II)center dot center dot center dot Mn(II) interactions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2013-08-22 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/1889]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 |
| 推荐引用方式 GB/T 7714 | Zhao, Yang,Zhang, Suyun,Zheng, Lina,et al. Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand:Synthesis, Crystal Structure and Magnetic Property[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2011,637(10):1304-1307. |
| APA | Zhao, Yang,Zhang, Suyun,Zheng, Lina,&Li, Yahong.(2011).Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand:Synthesis, Crystal Structure and Magnetic Property.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,637(10),1304-1307. |
| MLA | Zhao, Yang,et al."Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand:Synthesis, Crystal Structure and Magnetic Property".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 637.10(2011):1304-1307. |
入库方式： OAI收割
来源：青海盐湖研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。