Neutral cuprous complexes as ratiometric oxygen gas sensors
文献类型：期刊论文
| 作者 | Liu XH ; Sun W ; Zou LY ; Xie ZY ; Li X ; Lu CZ ; Wang LX ; Cheng YX |
| 刊名 | dalton transactions
 |
| 出版日期 | 2012 |
| 卷号 | 41期号:4页码:1312-1319 |
| 关键词 | DUAL EMISSION CU(I) COMPLEXES PHOTOPHYSICAL PROPERTIES EXCITED-STATE II COMPLEXES LIGANDS TEMPERATURE |
| ISSN号 | 1477-9226 |
| 通讯作者 | cheng yx |
| 中文摘要 | four neutral mononuclear cu(i) complexes, [cu(pyin)(pph(3))(2)] (1a), [cu(pyin)(dpephos)] (1b), [cu(quin)(pph(3))(2)] (2a) and [cu(quin)(dpephos)] (2b) (hpyin = 2-(2-pyridyl) indole, hquin = 2-(2-quinolyl)indole and dpephos = bis(2-(diphenylphosphino)phenyl)ether) have been synthesized. x-ray crystal structure analysis revealed that the central cu(i) ion in all complexes is in a distorted tetrahedral coordination environment. all four complexes display the typical metal-to-ligand charge transfer (mlct) absorption band at 371, 363, 413 and 402 nm, respectively. no emission was observed from any complexes in the solid state due to triplet-triplet annihilation. however, the complexes show unusual dual-emission originating from intraligand charge-transfer (ilct) and mlct transitions, when dispersed in a rigid matrix (e. g. pmma) or in frozen ch(2)cl(2). the oxidation potential of cu(i)/cu(ii) in these neutral complexes, similar to 0.5 v (vs. ag/agcl), is lower than those of cationic cu(i) complexes. films containing 10 wt% of these complexes in pmma shows ratiometric fluorescent oxygen gas sensing property with a response ratio of 0.3-3.2 and response time of 3-4 s. complex 2b acts as a ratiometric oxygen gas sensor with good reversibility through energy and electron transfer mechanisms under the loss of a counteranion. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000299054200029 |
| 公开日期 | 2013-08-29 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48723]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu XH,Sun W,Zou LY,et al. Neutral cuprous complexes as ratiometric oxygen gas sensors[J]. dalton transactions,2012,41(4):1312-1319. |
| APA | Liu XH.,Sun W.,Zou LY.,Xie ZY.,Li X.,...&Cheng YX.(2012).Neutral cuprous complexes as ratiometric oxygen gas sensors.dalton transactions,41(4),1312-1319. |
| MLA | Liu XH,et al."Neutral cuprous complexes as ratiometric oxygen gas sensors".dalton transactions 41.4(2012):1312-1319. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。