Cyano-bridged terbium(III)-chromium(III) bimetallic quasi-one-dimensional assembly exhibiting long-range magnetic ordering
文献类型：期刊论文
| 作者 | Guo Y ; Xu GF ; Wang C ; Cao TT ; Tang JK ; Liu ZQ ; Ma Y ; Yan SP ; Cheng P ; Liao DZ |
| 刊名 | dalton transactions
 |
| 出版日期 | 2012 |
| 卷号 | 41期号:5页码:1624-1629 |
| 关键词 | SINGLE-MOLECULE MAGNETS X-RAY-DIFFRACTION CHAIN MAGNETS COORDINATION POLYMERS CRYSTAL-STRUCTURE MULTIFUNCTIONAL MATERIALS LN(3+)-M3+ COMPLEXES NITRONYL NITROXIDE ORGANIC RADICALS DESIGNER MAGNETS |
| ISSN号 | 1477-9226 |
| 通讯作者 | tang jk |
| 中文摘要 | a new cyano-bridged tb(iii)-cr(iii) heterometallic complex [tb(h(2)o)(2)(dmf)(4){cr(cn)(6)}]center dot h(2)o (dmf = dimethylformamide) (1), assembled from paramagnetic hexacyanochromium(iii) [cr(cn)(6)](3-) building block and highly anisotropic terbium(iii) ion has been prepared and structurally and magnetically characterized. complex 1 shows one-dimensional (1d) zig-zag chain-like structural motif which is further extended into three-dimensional network through hydrogen-bonding interactions. the long-range magnetic ordering observed in complex 1, which is possibly due to interchain magnetic dipolar interactions, illuminates that this complex is a molecule-based magnet with critical temperature of about 5 k. this higher critical temperature among those of ln(iii)-cr(iii) heterometallic complexes exhibiting long-range magnetic ordering is probably due to the introduction of highly anisotropic terbium(iii) ion. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000299054500029 |
| 公开日期 | 2013-08-29 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48725]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Guo Y,Xu GF,Wang C,et al. Cyano-bridged terbium(III)-chromium(III) bimetallic quasi-one-dimensional assembly exhibiting long-range magnetic ordering[J]. dalton transactions,2012,41(5):1624-1629. |
| APA | Guo Y.,Xu GF.,Wang C.,Cao TT.,Tang JK.,...&Liao DZ.(2012).Cyano-bridged terbium(III)-chromium(III) bimetallic quasi-one-dimensional assembly exhibiting long-range magnetic ordering.dalton transactions,41(5),1624-1629. |
| MLA | Guo Y,et al."Cyano-bridged terbium(III)-chromium(III) bimetallic quasi-one-dimensional assembly exhibiting long-range magnetic ordering".dalton transactions 41.5(2012):1624-1629. |
入库方式： OAI收割
来源：长春应用化学研究所
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