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An experimental study on synthesis of glycolic acid via carbonylation of formaldehyde using PTFE membrane contactor

文献类型：期刊论文

作者Zhu, Zhihao1,2; Kang, Guodong2; Sun, Ying2; Yu, Sha1,2; Li, Meng2; Xu, Jie2; Cao, Yiming2
刊名JOURNAL OF MEMBRANE SCIENCE
出版日期2019-09-15
卷号586页码:259-266
ISSN号0376-7388
关键词Carbonylation of formaldehyde Glycolic acid PTFE Membrane contactor Mass transfer
DOI10.1016/j.memsci.2019.05.073
通讯作者Kang, Guodong(kangguod@dicp.ac.cn) ; Cao, Yiming(ymcao@dicp.ac.cn)
英文摘要The batch and continuous synthesis of glycolic acid via carbonylation of formaldehyde using high-temperature and high-pressure poly(tetrafluoroethylene) (PTFE) membrane contactor was demonstrated in this paper. The experiments in conventional stirred tank reactor were also conducted for comparison. The results showed that the yield of glycolic acid was significantly improved in membrane contactor system compared to the stirred tank reactor. At reaction temperature of 120 degrees C and reaction pressure of 5.0 MPa, the yield of glycolic acid was higher than 90% when the reaction time was 1 h, while it was only about 45% in the conventional stirred tank reactor. The enhancement of yield was due to the improvement of mass transfer or dispersion of CO in membrane contactor system, which could provide larger gas-liquid contact area and shorter mass transfer distance. The stability of PTFE hollow fibre membranes was also investigated by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), liquid entry pressure (LEP), bubble point (BP) and contact angle (CA) measurements. The characterizations indicated that PTFE membranes exhibited good chemical and thermal stability in this reaction system. This study provided new idea and reference for the carbonylation of formaldehyde and similar gas-liquid reactions.
WOS关键词VAPOR-PHASE CARBONYLATION ; HOLLOW-FIBER MEMBRANES ; ETHYLENE-GLYCOL ; METHYL FORMATE ; DIMETHOXYMETHANE ; HETEROPOLYACIDS ; PRECURSORS ; CATALYSTS
资助项目DICP[DMTO201604] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[2016171] ; LiaoNing Revitalization Talents Program[XLYC1807240]
WOS研究方向Engineering ; Polymer Science
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000471097100027
资助机构DICP ; DICP ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; LiaoNing Revitalization Talents Program ; DICP ; DICP ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; LiaoNing Revitalization Talents Program ; DICP ; DICP ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; LiaoNing Revitalization Talents Program ; DICP ; DICP ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; LiaoNing Revitalization Talents Program
源URL[http://cas-ir.dicp.ac.cn/handle/321008/172174]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Kang, Guodong; Cao, Yiming
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714		 Zhu, Zhihao,Kang, Guodong,Sun, Ying,et al. An experimental study on synthesis of glycolic acid via carbonylation of formaldehyde using PTFE membrane contactor[J]. JOURNAL OF MEMBRANE SCIENCE,2019,586:259-266.
APA Zhu, Zhihao.,Kang, Guodong.,Sun, Ying.,Yu, Sha.,Li, Meng.,...&Cao, Yiming.(2019).An experimental study on synthesis of glycolic acid via carbonylation of formaldehyde using PTFE membrane contactor.JOURNAL OF MEMBRANE SCIENCE,586,259-266.
MLA Zhu, Zhihao,et al."An experimental study on synthesis of glycolic acid via carbonylation of formaldehyde using PTFE membrane contactor".JOURNAL OF MEMBRANE SCIENCE 586(2019):259-266.

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来源：大连化学物理研究所

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