Microfluidic Synthesis of UiO-66 Metal-organic Frameworks Modified with Different Functional Groups
文献类型：期刊论文
| 作者 | Sheng Bingchen1; Li Cong1; Liu Yingya1; Wang Anjie1; Wang Yao1; Zhang Jian2; Liu Weixu1 |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2019-07-10 |
| 卷号 | 40期号:7页码:1365-1373 |
| ISSN号 | 0251-0790 |
| 关键词 | Metal-organic framework UiO-66 Nanomaterial Microfluidic synthesis |
| DOI | 10.7503/cjcu20180831 |
| 通讯作者 | Wang Yao(wangyao@dlut.edu.cn) |
| 英文摘要 | Zirconium based metal-organic framework UiO-66 was synthesized continuously by microfluidic method. Compared with the traditional solvothermal synthesis in batch reactors, microfluidic synthesis is more efficient. It has the advantages in highly efficient mixing and heat transfer, thus lead to enhanced reaction rates. Microfluidic synthesis can obtain uniform hexahedral crystalline products in nanometer range(less than 100 nm). The influences of temperature, total flowrate and residence time on the obtained products were investigated. Higher temperature benefited the growth of crystal. When flowrate increased, crystal sizes of UiO-66 synthesized by microfluidic method decreased. Crystal growth required sufficient residence time (20 min), but if the residence time was prolonged further, the crystal particle size would not change any more. By optimizing the synthetic parameters, UiO-66 modified with different functional groups, UiO-66-X (X = NH2, NO2, Br), could be synthesized continuously by microfluidic synthesis. |
| WOS关键词 | SIZE ; DESIGN ; FLOW |
| 资助项目 | National Key R&D Program of China[2016YFE0109800] ; National Natural Science Foundation of China[21473017] ; National Natural Science Foundation of China[21373215] ; Fundamental Research Funds for the Central Universities, China[DUT17JC20] ; Open Project of the State Key Laboratory of Fine Chemicals, China[KF1405] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | HIGHER EDUCATION PRESS |
| WOS记录号 | WOS:000490720100005 |
| 资助机构 | National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities, China ; Fundamental Research Funds for the Central Universities, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities, China ; Fundamental Research Funds for the Central Universities, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities, China ; Fundamental Research Funds for the Central Universities, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities, China ; Fundamental Research Funds for the Central Universities, China ; Open Project of the State Key Laboratory of Fine Chemicals, China ; Open Project of the State Key Laboratory of Fine Chemicals, China |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/172394]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang Yao |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem Engn, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Lab Catalysts & New Mat, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sheng Bingchen,Li Cong,Liu Yingya,et al. Microfluidic Synthesis of UiO-66 Metal-organic Frameworks Modified with Different Functional Groups[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2019,40(7):1365-1373. |
| APA | Sheng Bingchen.,Li Cong.,Liu Yingya.,Wang Anjie.,Wang Yao.,...&Liu Weixu.(2019).Microfluidic Synthesis of UiO-66 Metal-organic Frameworks Modified with Different Functional Groups.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,40(7),1365-1373. |
| MLA | Sheng Bingchen,et al."Microfluidic Synthesis of UiO-66 Metal-organic Frameworks Modified with Different Functional Groups".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 40.7(2019):1365-1373. |
入库方式： OAI收割
来源：大连化学物理研究所
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