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Transformation of Polyoxometalate into 3D Porous Li-Containing Oxide: A Case Study of gamma-LiV2O5 for High-Performance Cathodes of Li-Ion Batteries

文献类型：期刊论文

作者Bayaguud, Aruuhan2; Zhang, Zhibo2; Geng, Maoning2; Fu, Yanpeng3; Yu, Yan1,4,5; Zhu, Changbao2
刊名SMALL METHODS
出版日期2019-10-01
卷号3期号:10页码:9
ISSN号2366-9608
关键词3D porous films electrostatic spray deposition high-capacity cathodes lithium vanadium oxide polyoxometalate
DOI10.1002/smtd.201900187
通讯作者Yu, Yan(yanyumse@ustc.edu.cn) ; Zhu, Changbao(zhuchb6@mail.sysu.edu.cn)
英文摘要The development of cathode materials with high Li storage capacity and fast Li-ion diffusion kinetics is considered to be a promising way to extend the energy and power densities of Li-ion batteries (LIBs). As potential high-capacity cathode materials for LIBs, polyoxometalates (POMs) suffer greatly from inherent drawbacks. Therefore, another possibility for the application of POMs in LIBs is shown, which is to transform POMs into relevant 3D porous Li-containing oxides. Here, a unique 3D porous gamma-LiV2O5 film is successfully prepared by combining the electrostatic spray deposition technique and the POM as a precursor. Outstanding high capacity with stable cycling performance and excellent rate capability is realized based on 3D porous nanostructure and thin-film morphology, which effectively facilitate the transport of both lithium ion and electron. Moreover, this work demonstrates the feasibility of achieving high-performance metal oxide cathode by the transformation of POMs and also shows the superiority of gamma-phase over alpha-phase as a starting cathode material in LIBs as well.
WOS关键词LITHIUM VANADIUM-OXIDE ; SOLVOTHERMAL SYNTHESIS ; CLUSTER ; INTERCALATION ; BRONZES ; STORAGE ; MICROSPHERES ; REFINEMENT ; PENTOXIDE ; NANORODS
资助项目National Key R&D Program of China[2018YFB0905400] ; National Natural Science Foundation of China[51702376] ; National Natural Science Foundation of China[51622210] ; National Natural Science Foundation of China[51872277] ; Fundamental Research Funds for the Central Universities[WK3430000004] ; DNL Cooperation Fund, CAS[DNL180310] ; National Thousand Youth Talents Project of the Chinese Government
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000490288400017
资助机构National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; National Thousand Youth Talents Project of the Chinese Government ; National Thousand Youth Talents Project of the Chinese Government ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; National Thousand Youth Talents Project of the Chinese Government ; National Thousand Youth Talents Project of the Chinese Government ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; National Thousand Youth Talents Project of the Chinese Government ; National Thousand Youth Talents Project of the Chinese Government ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; National Thousand Youth Talents Project of the Chinese Government ; National Thousand Youth Talents Project of the Chinese Government
源URL[http://cas-ir.dicp.ac.cn/handle/321008/172496]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Yu, Yan; Zhu, Changbao
作者单位1.Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
2.Sun Yat Sen Univ, Dept Mat Sci & Engn, Guangzhou 510275, Guangdong, Peoples R China
3.Guangdong Univ Technol, Sch Mat & Energy, Guangzhou 510006, Guangdong, Peoples R China
4.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Dept Mat Sci & Engn, Key Lab Mat Energy Convers,CAS, Hefei 230026, Anhui, Peoples R China
5.Chinese Acad Sci, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714		 Bayaguud, Aruuhan,Zhang, Zhibo,Geng, Maoning,et al. Transformation of Polyoxometalate into 3D Porous Li-Containing Oxide: A Case Study of gamma-LiV2O5 for High-Performance Cathodes of Li-Ion Batteries[J]. SMALL METHODS,2019,3(10):9.
APA Bayaguud, Aruuhan,Zhang, Zhibo,Geng, Maoning,Fu, Yanpeng,Yu, Yan,&Zhu, Changbao.(2019).Transformation of Polyoxometalate into 3D Porous Li-Containing Oxide: A Case Study of gamma-LiV2O5 for High-Performance Cathodes of Li-Ion Batteries.SMALL METHODS,3(10),9.
MLA Bayaguud, Aruuhan,et al."Transformation of Polyoxometalate into 3D Porous Li-Containing Oxide: A Case Study of gamma-LiV2O5 for High-Performance Cathodes of Li-Ion Batteries".SMALL METHODS 3.10(2019):9.

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来源：大连化学物理研究所

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