Covalent Functionalization of Graphene Oxide with a Presynthesized Metal-Organic Framework Enables a Highly Stable Electrochemical Sensing
文献类型：期刊论文
| 作者 | Fu, Junhong2; Wang, Xiuyun1; Wang, Tingting1; Zhang, Jie1; Guo, Song2; Wu, Shuo1; Zhu, Fenghui1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2019-09-11 |
| 卷号 | 11期号:36页码:33238-33244 |
| 关键词 | covalent functionalization graphene oxide metal-organic framework electrochemical sensing purine derivatives |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.9b10531 |
| 通讯作者 | Wang, Xiuyun(xiuyun@dlut.edu.cn) |
| 英文摘要 | This paper reports the covalent functionalization of graphene oxide (GO) by a presynthesized metal-organic framework NH2-MIL-101(Fe) via ultrasonication of the two components. The formation of Fe-O covalent bonding in the NH2-MIL-101(Fe)-GO nanohybrid is clearly evidenced, and the covalent bonding still remains after electrochemical reduction. The morphology and structure of the nanohybrid are characterized via scanning electron microscopy, transmission electron microscopy, UV-vis spectroscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and Raman spectroscopy. The electrode based on electrochemically reduced NH2-MIL-101(Fe)-GO shows ultrastable and high-sensitive performance in simultaneous electrochemical sensing of three purine metabolic derivatives (uric acid, xanthine, and hypoxanthine); in particular, no signal fading is seen even after running for 120 times. The covalent bonding within the nanohybrid is obviously the key to maintain such a stability. |
| WOS关键词 | COMPOSITES |
| 资助项目 | National Natural Science Foundation of China[21205008] ; National Natural Science Foundation of China[21703235] ; Fundamental Research Funds for the Central Universities[DUT16LK25] ; Postdoctoral International Exchange Fellowship Program |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000486360500069 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Postdoctoral International Exchange Fellowship Program ; Postdoctoral International Exchange Fellowship Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Postdoctoral International Exchange Fellowship Program ; Postdoctoral International Exchange Fellowship Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Postdoctoral International Exchange Fellowship Program ; Postdoctoral International Exchange Fellowship Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Postdoctoral International Exchange Fellowship Program ; Postdoctoral International Exchange Fellowship Program |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/172553]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Xiuyun |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Gold Catalysis Res Ctr, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, Junhong,Wang, Xiuyun,Wang, Tingting,et al. Covalent Functionalization of Graphene Oxide with a Presynthesized Metal-Organic Framework Enables a Highly Stable Electrochemical Sensing[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(36):33238-33244. |
| APA | Fu, Junhong.,Wang, Xiuyun.,Wang, Tingting.,Zhang, Jie.,Guo, Song.,...&Zhu, Fenghui.(2019).Covalent Functionalization of Graphene Oxide with a Presynthesized Metal-Organic Framework Enables a Highly Stable Electrochemical Sensing.ACS APPLIED MATERIALS & INTERFACES,11(36),33238-33244. |
| MLA | Fu, Junhong,et al."Covalent Functionalization of Graphene Oxide with a Presynthesized Metal-Organic Framework Enables a Highly Stable Electrochemical Sensing".ACS APPLIED MATERIALS & INTERFACES 11.36(2019):33238-33244. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。