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Ru/H-beta as an efficient catalyst for the conversion of furfural into 3-acetyl-1-propanol (3-AP) toward one-pot transformation of xylan to 3-AP

文献类型：期刊论文

作者Liu, Qiaoyun2; Liu, Fei2; Zhang, Yaru1,2; Su, Yang2; Wang, Aiqin2,3; Zhang, Tao2,3
刊名MOLECULAR CATALYSIS
出版日期2019-10-01
卷号476页码:6
关键词Biomass Furfural 3-acetyl-1-propanol Carbohydrates Ru-based bifunctional catalysts
ISSN号2468-8231
DOI10.1016/j.mcat.2019.110506
通讯作者Liu, Fei() ; Zhang, Tao(taozhang@dicp.ac.cn)
英文摘要A highly active and robust catalyst composed of Ru nanoparticles highly dispersed on zeolite H-beta was developed for transforming furfural into 3-acetyl-1-propanol (3-AP) in good yield (81%)under mild conditions (80 degrees C, 1 MPa H-2). Both the support nature and the preparation methods had significant impacts on the dispersion of Ru, eventually on the yield of 3-AP. Ion-exchange method proved best for obtaining the highly active and selective catalyst for this reaction. Moreover, the catalyst can be regenerated easily by calcination and reduction. This catalyst was further explored for the one-pot conversion of xylose and xylan to 3-AP with a yield of 46% and 31%, respectively, thus opening a new feasible pathway from biomass to valuable fine chemicals.
WOS关键词SELECTIVE OXIDATION ; ALCOHOLS ; SOLVENT ; 1,5-PENTANEDIOL ; HYDROGENATION ; CHEMICALS ; PLATFORM ; ALKANES ; WATER ; ACID
资助项目National Key Projects for Fundamental Research and Development of China[2018YF1501602] ; National Key Projects for Fundamental Research and Development of China[2016YFA0202801] ; National Natural Science Foundation of China[21606227] ; National Natural Science Foundation of China[21690080] ; National Natural Science Foundation of China[21690084] ; National Natural Science Foundation of China[21721004] ; National Natural Science Foundation of China[21673228] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020100] ; Dalian National Laboratory for Clean Energy[DNL180303]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000488661800019
出版者ELSEVIER
资助机构National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Dalian National Laboratory for Clean Energy ; Dalian National Laboratory for Clean Energy ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Dalian National Laboratory for Clean Energy ; Dalian National Laboratory for Clean Energy ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Dalian National Laboratory for Clean Energy ; Dalian National Laboratory for Clean Energy ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Dalian National Laboratory for Clean Energy ; Dalian National Laboratory for Clean Energy
源URL[http://cas-ir.dicp.ac.cn/handle/321008/172601]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Liu, Fei; Zhang, Tao
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Key Lab Sci & Technol Appl Catalysis, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714		 Liu, Qiaoyun,Liu, Fei,Zhang, Yaru,et al. Ru/H-beta as an efficient catalyst for the conversion of furfural into 3-acetyl-1-propanol (3-AP) toward one-pot transformation of xylan to 3-AP[J]. MOLECULAR CATALYSIS,2019,476:6.
APA Liu, Qiaoyun,Liu, Fei,Zhang, Yaru,Su, Yang,Wang, Aiqin,&Zhang, Tao.(2019).Ru/H-beta as an efficient catalyst for the conversion of furfural into 3-acetyl-1-propanol (3-AP) toward one-pot transformation of xylan to 3-AP.MOLECULAR CATALYSIS,476,6.
MLA Liu, Qiaoyun,et al."Ru/H-beta as an efficient catalyst for the conversion of furfural into 3-acetyl-1-propanol (3-AP) toward one-pot transformation of xylan to 3-AP".MOLECULAR CATALYSIS 476(2019):6.

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来源：大连化学物理研究所

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