中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 大连化学物理研究所
  3. 中国科学院大连化学物理研究所
Self-Supported and Flexible Sulfur Cathode Enabled via Synergistic Confinement for High-Energy-Density Lithium-Sulfur Batteries

文献类型：期刊论文

作者Wang, Zhuosen4; Shen, Jiadong4; Liu, Jun2,4; Xu, Xijun; Liu, Zhengbo4; Hu, Renzong4; Yang, Lichun4; Feng, Yuezhan1; Shi, Zhicong2; Ouyang, Liuzhang4
刊名ADVANCED MATERIALS
出版日期2019-08-01
卷号31期号:33页码:11
关键词flexible electrodes high sulfur loading Li-S batteries self-supported arrays synergistic confinement
ISSN号0935-9648
DOI10.1002/adma.201902228
通讯作者Liu, Jun(msjliu@scut.edu.cn) ; Yu, Yan(yanyumse@ustc.edu.cn) ; Zhu, Min(memzhu@scut.edu.cn)
英文摘要Lithium-sulfur (Li-S) batteries have attracted much attention in the field of electrochemical energy storage due to their high energy density and low cost. However, the "shuttle effect" of the sulfur cathode, resulting in poor cyclic performance, is a big barrier for the development of Li-S batteries. Herein, a novel sulfur cathode integrating sulfur, flexible carbon cloth, and metal-organic framework (MOF)-derived N-doped carbon nanoarrays with embedded CoP (CC@CoP/C) is designed. These unique flexible nanoarrays with embedded polar CoP nanoparticles not only offer enough voids for volume expansion to maintain the structural stability during the electrochemical process, but also promote the physical encapsulation and chemical entrapment of all sulfur species. Such designed CC@CoP/C cathodes with synergistic confinement (physical adsorption and chemical interactions) for soluble intermediate lithium polysulfides possess high sulfur loadings (as high as 4.17 mg cm(-2)) and exhibit large specific capacities at different C-rates. Specially, an outstanding long-term cycling performance can be reached. For example, an ultralow decay of 0.016% per cycle during the whole 600 cycles at a high current density of 2C is displayed. The current work provides a promising design strategy for high-energy-density Li-S batteries.
WOS关键词N-DOPED CARBON ; EFFICIENT ELECTROCATALYST ; POLYSULFIDE ; PERFORMANCE ; GRAPHENE ; COMPOSITES ; POWER ; NANOPARTICLES ; NANOFIBERS ; FRAMEWORK
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
WOS记录号WOS:000481909600001
出版者WILEY-V C H VERLAG GMBH
源URL[http://cas-ir.dicp.ac.cn/handle/321008/172947]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Liu, Jun; Yu, Yan; Zhu, Min
作者单位1.Zhengzhou Univ, Minist Educ, Key Lab Mat Proc & Mold, Zhengzhou 450002, Henan, Peoples R China
2.Guangdong Univ Technol, Sch Mat & Energy, Smart Energy Res Ctr, Guangdong Prov Key Lab Funct Soft Condensed Matte, Guangzhou 510000, Guangdong, Peoples R China
3.Univ Sci & Technol China, Chinese Acad Sci, Key Lab Mat Energy Convers, Hefei Natl Lab Phys Sci Microscale,Dept Mat Sci &, Hefei 230026, Anhui, Peoples R China
4.South China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Guangdong, Peoples R China
5.Chinese Acad Sci, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714		 Wang, Zhuosen,Shen, Jiadong,Liu, Jun,et al. Self-Supported and Flexible Sulfur Cathode Enabled via Synergistic Confinement for High-Energy-Density Lithium-Sulfur Batteries[J]. ADVANCED MATERIALS,2019,31(33):11.
APA Wang, Zhuosen.,Shen, Jiadong.,Liu, Jun.,Xu, Xijun.,Liu, Zhengbo.,...&Zhu, Min.(2019).Self-Supported and Flexible Sulfur Cathode Enabled via Synergistic Confinement for High-Energy-Density Lithium-Sulfur Batteries.ADVANCED MATERIALS,31(33),11.
MLA Wang, Zhuosen,et al."Self-Supported and Flexible Sulfur Cathode Enabled via Synergistic Confinement for High-Energy-Density Lithium-Sulfur Batteries".ADVANCED MATERIALS 31.33(2019):11.

入库方式： OAI收割

来源：大连化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。