Construction of a Stable Crystalline Polyimide Porous Organic Framework for C2H2/C2H4 and CO2/N-2 Separation
文献类型：期刊论文
| 作者 | Jiang, Lingchang1; Wang, Pengyuan1,3; Li, Meiping1; Zhang, Panpan2; Li, Jialu1; Liu, Jia1; Ma, Yanhang4; Ren, Hao1; Zhu, Guangshan1,2 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2019-07-05 |
| 卷号 | 25期号:38页码:9045-9051 |
| 关键词 | adsorption gas separation polymerization polymers porous organic frameworks |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201900857 |
| 通讯作者 | Liu, Jia(jia@jlu.edu.cn) ; Ren, Hao(renhao@jlu.edu.cn) |
| 英文摘要 | Utilization of porous materials for gas capture and separation is a hot research topic. Removal of acetylene (C2H2) from ethylene (C2H4) is important in the oil refining and petrochemical industries, since C2H2 impurities deactivate the catalysts and terminate the polymerization of C2H4. Carbon dioxide (CO2) emission from power plants contributes to global climate change and threatens the survival of life on this planet. Herein, 2D crystalline polyimide porous organic framework PAF-120, which was constructed by imidization of linear naphthalene-1,4,5,8-tetracarboxylic dianhydride and triangular 1,3,5-tris(4-aminophenyl)benzene, showed significant thermal and chemical stability. Low-pressure gas adsorption isotherms revealed that PAF-120 exhibits good selective adsorption of C2H2 over C2H4 and CO2 over N-2. At 298 K and 1 bar, its C2H2 and CO2 selectivities were predicted to be 4.1 and 68.7, respectively. More importantly, PAF-120 exhibits the highest selectivity for C2H2/C2H4 separation among porous organic frameworks. Thus PAF-120 could be a suitable candidate for selective separation of C2H2 over C2H4 and CO2 over N-2. |
| WOS关键词 | AROMATIC FRAMEWORK ; CARBON-DIOXIDE ; EFFICIENT ; CO2 ; ETHYLENE ; STORAGE ; THERMODYNAMICS ; STABILITY ; MEMBRANE ; HYDROGEN |
| 资助项目 | National Natural Science Foundation of China (NSFC)[21531003] ; National Natural Science Foundation of China (NSFC)[21501024] ; National Natural Science Foundation of China (NSFC)[91622106] ; National Natural Science Foundation of China (NSFC)[21875140] ; 111 program ; National Basic Research Program of China (973 Program)[2014CB931804] ; National Basic Research Program of China (973 Program)[2012CB821700] ; Commission for Science and Technology of Shanghai Municipality[17ZR1418600] ; Young Elite Scientist Sponsorship Program by CAST[2017QNRC001] ; CEM, SPST, ShanghaiTech |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000484146600018 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; 111 program ; 111 program ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; Commission for Science and Technology of Shanghai Municipality ; Commission for Science and Technology of Shanghai Municipality ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; CEM, SPST, ShanghaiTech ; CEM, SPST, ShanghaiTech ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; 111 program ; 111 program ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; Commission for Science and Technology of Shanghai Municipality ; Commission for Science and Technology of Shanghai Municipality ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; CEM, SPST, ShanghaiTech ; CEM, SPST, ShanghaiTech ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; 111 program ; 111 program ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; Commission for Science and Technology of Shanghai Municipality ; Commission for Science and Technology of Shanghai Municipality ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; CEM, SPST, ShanghaiTech ; CEM, SPST, ShanghaiTech ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; 111 program ; 111 program ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; Commission for Science and Technology of Shanghai Municipality ; Commission for Science and Technology of Shanghai Municipality ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; CEM, SPST, ShanghaiTech ; CEM, SPST, ShanghaiTech |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/173139]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Liu, Jia; Ren, Hao |
| 作者单位 | 1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China 2.Northeast Normal Univ, Fac Chem, Key Lab Polyoxometalate Sci, Minist Educ, Changchun 130024, Jilin, Peoples R China 3.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 4.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Lingchang,Wang, Pengyuan,Li, Meiping,et al. Construction of a Stable Crystalline Polyimide Porous Organic Framework for C2H2/C2H4 and CO2/N-2 Separation[J]. CHEMISTRY-A EUROPEAN JOURNAL,2019,25(38):9045-9051. |
| APA | Jiang, Lingchang.,Wang, Pengyuan.,Li, Meiping.,Zhang, Panpan.,Li, Jialu.,...&Zhu, Guangshan.(2019).Construction of a Stable Crystalline Polyimide Porous Organic Framework for C2H2/C2H4 and CO2/N-2 Separation.CHEMISTRY-A EUROPEAN JOURNAL,25(38),9045-9051. |
| MLA | Jiang, Lingchang,et al."Construction of a Stable Crystalline Polyimide Porous Organic Framework for C2H2/C2H4 and CO2/N-2 Separation".CHEMISTRY-A EUROPEAN JOURNAL 25.38(2019):9045-9051. |
入库方式： OAI收割
来源：大连化学物理研究所
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