Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines
文献类型：期刊论文
| 作者 | Xue, Feng1; Liu, Qibin2; Zhu, Yong1; Qing, Yunfei1; Wan, Boshun3 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2019-08-18 |
| 卷号 | 9期号:44页码:25377-25381 |
| DOI | 10.1039/c9ra04836g |
| 通讯作者 | Xue, Feng(fxuehist@sina.com) ; Liu, Qibin(qliu@allychem.com) ; Wan, Boshun(bswan@dicp.ac.cn) |
| 英文摘要 | An efficient Rh-catalyzed addition of arylboronic acids to N-tosylarylimines has been developed with chiral benzene backbone-based sulfoxide-olefin ligands, where 2-methoxy-1-naphthyl sulfinyl functionalized olefin ligands have shown to be more effective. The versatile method tolerates a wide range of functional groups and shows broad scope without regard to electronic or steric substitution pattern, allowing access to a broad range of chiral diarylmethylamines in high yields (up to 99%) with excellent enantioselectivities (up to 99% ee). |
| WOS关键词 | ASYMMETRIC CONJUGATE ADDITION ; ORGANOBORONIC ACIDS ; SULFUR-OLEFINS ; DIENE LIGANDS ; ARYLATION ; CONSTRUCTION ; ACCESS |
| 资助项目 | National Natural Science Foundation of China[21172218] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000481879400013 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/173288]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Xue, Feng; Liu, Qibin; Wan, Boshun |
| 作者单位 | 1.Henan Inst Sci & Technol, Coll Chem & Chem Engn, Key Lab Funct Organ Mol Xinxiang City Henan Prov, Xinxiang 453002, Henan, Peoples R China 2.Dalian Allychem Co Ltd, 5 Jinbin Rd, Dalian 116620, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, Feng,Liu, Qibin,Zhu, Yong,et al. Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines[J]. RSC ADVANCES,2019,9(44):25377-25381. |
| APA | Xue, Feng,Liu, Qibin,Zhu, Yong,Qing, Yunfei,&Wan, Boshun.(2019).Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines.RSC ADVANCES,9(44),25377-25381. |
| MLA | Xue, Feng,et al."Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines".RSC ADVANCES 9.44(2019):25377-25381. |
入库方式： OAI收割
来源：大连化学物理研究所
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