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Chiral sensors for determining the absolute configurations of alpha-amino acid derivatives

文献类型：期刊论文

作者Chen, Zhongxiang1,2; Fan, Hongjun3; Yang, Shiwei1,2; Bian, Guangling1,2; Song, Ling1,2
刊名ORGANIC & BIOMOLECULAR CHEMISTRY
出版日期2018-10-07
卷号16期号:37页码:8311-8317
ISSN号1477-0520
DOI10.1039/c8ob01933a
通讯作者Bian, Guangling(glb@fjirsm.ac.cn) ; Song, Ling(songling@fjirsm.ac.cn)
英文摘要A simple strategy for configurational assignments of alpha-amino acids has been developed by comparison of the proton NMR chemical shift values of the alpha hydrogens of N-phthaloyl protected alphaamino acids in the presence of (R)-CSA 1 and (S)-CSA 1, respectively. Highly resolved NMR spectra can be obtained directly on the mixed solution of the chiral solvating agents with N-phthaloyl protected alphaamino acids in NMR tubes, giving well distinguishable proton signals without interference which dramatically improve the accuracy of assignment and hasten the assigning procedure. The strategy is widely applicable for varied natural and non-natural amino acids.
WOS关键词NMR-SPECTROSCOPY ; SOLVATING AGENTS ; ENANTIOSELECTIVE RECOGNITION ; SHIFT-REAGENT ; HYDROXY ACIDS ; DISCRIMINATION ; ASSIGNMENT ; VERSATILE ; COMPLEXATION ; ENANTIOMERS
资助项目Chinese Academy of Sciences[XDB20000000] ; DICP[DICP DMTO201404] ; Natural Science Foundation of Fujian Province, China[2018J01029] ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000483966100013
出版者ROYAL SOC CHEMISTRY
资助机构Chinese Academy of Sciences ; Chinese Academy of Sciences ; DICP ; DICP ; Natural Science Foundation of Fujian Province, China ; Natural Science Foundation of Fujian Province, China ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; DICP ; DICP ; Natural Science Foundation of Fujian Province, China ; Natural Science Foundation of Fujian Province, China ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; DICP ; DICP ; Natural Science Foundation of Fujian Province, China ; Natural Science Foundation of Fujian Province, China ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; DICP ; DICP ; Natural Science Foundation of Fujian Province, China ; Natural Science Foundation of Fujian Province, China ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences
源URL[http://cas-ir.dicp.ac.cn/handle/321008/173302]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Bian, Guangling; Song, Ling
作者单位1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714		 Chen, Zhongxiang,Fan, Hongjun,Yang, Shiwei,et al. Chiral sensors for determining the absolute configurations of alpha-amino acid derivatives[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2018,16(37):8311-8317.
APA Chen, Zhongxiang,Fan, Hongjun,Yang, Shiwei,Bian, Guangling,&Song, Ling.(2018).Chiral sensors for determining the absolute configurations of alpha-amino acid derivatives.ORGANIC & BIOMOLECULAR CHEMISTRY,16(37),8311-8317.
MLA Chen, Zhongxiang,et al."Chiral sensors for determining the absolute configurations of alpha-amino acid derivatives".ORGANIC & BIOMOLECULAR CHEMISTRY 16.37(2018):8311-8317.

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来源：大连化学物理研究所

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