Effectiveness of metal oxide catalysts for the degradation of 1,4-dioxane
文献类型：期刊论文
| 作者 | Heck, Kimberly N.1; Wang, Yehong2; Wu, Gang3; Wang, Feng2; Tsai, Ah-Lim3; Adamson, David T.4; Wong, Michael S.1,5,6,7,8 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2019-08-27 |
| 卷号 | 9期号:46页码:27042-27049 |
| DOI | 10.1039/c9ra05007h |
| 通讯作者 | Wong, Michael S.(mswong@rice.edu) |
| 英文摘要 | 1,4-dioxane, commonly used as a solvent stabilizer and industrial solvent, is an environmental contaminant and probable carcinogen. In this study, we explored the concept of using metal oxides to activate H2O2 catalytically at neutral pH in the dark for 1,4-dioxane degradation. Based on batch kinetics measurements, materials that displayed the most suitable characteristics (high 1,4-dioxane degradation activity and high H2O2 consumption efficiency) were ZrO2, WOx/ZrO2, and CuO. In contrast, materials like TiO2, WO3, and aluminosilicate zeolite Y exhibited both low 1,4-dioxane degradation and H2O2 consumption activities. Other materials (e.g., Fe2O3 and CeO2) consumed H2O2 rapidly, however 1,4-dioxane degradation was negligible. The supported metal oxide WOx/ZrO2 was the most active for 1,4-dioxane degradation and had higher H2O2 consumption efficiency compared to ZrO2. In situ acetonitrile poisoning and FTIR spectroscopy results indicate different surface acid sites for 1,4-dioxane and H2O2 adsorption and reaction. Electron paramagnetic resonance measurements indicate that H2O2 forms hydroxyl radicals (OH) in the presence of CuO, and unusually, forms superoxide/peroxyl radicals (O-2(-)) in the presence of WOx/ZrO2. The identified material properties suggest metal oxides/H2O2 as a potential advanced oxidation process in the treatment of 1,4-dioxane and other recalcitrant organic compounds. |
| WOS关键词 | ZERO-VALENT IRON ; HYDROGEN-PEROXIDE ; ELECTROCHEMICAL OXIDATION ; H2O2 DECOMPOSITION ; TRANSITION-METAL ; WASTE-WATER ; SURFACE ; ACTIVATION ; ANTIOXIDANTS ; ELECTRODES |
| 资助项目 | Strategic Environmental Research and Development Program (SERDP) award[ER-2307] ; NIH[NS094535] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000483739800057 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | Strategic Environmental Research and Development Program (SERDP) award ; Strategic Environmental Research and Development Program (SERDP) award ; NIH ; NIH ; Strategic Environmental Research and Development Program (SERDP) award ; Strategic Environmental Research and Development Program (SERDP) award ; NIH ; NIH ; Strategic Environmental Research and Development Program (SERDP) award ; Strategic Environmental Research and Development Program (SERDP) award ; NIH ; NIH ; Strategic Environmental Research and Development Program (SERDP) award ; Strategic Environmental Research and Development Program (SERDP) award ; NIH ; NIH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/173343]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wong, Michael S. |
| 作者单位 | 1.Rice Univ, Dept Chem & Biomol Engn, Houston, TX 77005 USA 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China 3.Univ Texas Med Sch Houston, Dept Internal Med, Div Hematol, Houston, TX 77030 USA 4.GSI Environm, Houston, TX 77098 USA 5.Dept Chem, Houston, TX 77005 USA 6.Dept Civil & Environm Engn, Houston, TX 77005 USA 7.Dept Mat Sci & Nano Engn, Houston, TX 77005 USA 8.Rice Univ, Ctr Nanoenabled Water Treatment, Houston, TX 77005 USA |
| 推荐引用方式 GB/T 7714 | Heck, Kimberly N.,Wang, Yehong,Wu, Gang,et al. Effectiveness of metal oxide catalysts for the degradation of 1,4-dioxane[J]. RSC ADVANCES,2019,9(46):27042-27049. |
| APA | Heck, Kimberly N..,Wang, Yehong.,Wu, Gang.,Wang, Feng.,Tsai, Ah-Lim.,...&Wong, Michael S..(2019).Effectiveness of metal oxide catalysts for the degradation of 1,4-dioxane.RSC ADVANCES,9(46),27042-27049. |
| MLA | Heck, Kimberly N.,et al."Effectiveness of metal oxide catalysts for the degradation of 1,4-dioxane".RSC ADVANCES 9.46(2019):27042-27049. |
入库方式： OAI收割
来源：大连化学物理研究所
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