Microstructural and Interfacial Designs of Oxygen-Permeable Membranes for Oxygen Separation and Reaction-Separation Coupling
文献类型：期刊论文
| 作者 | Zhu, Xuefeng; Yang, Weishen |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2019-08-16 |
| 页码 | 21 |
| ISSN号 | 0935-9648 |
| 关键词 | interfaces membrane reactors microstructure mixed ionic-electronic conductors oxygen permeation |
| DOI | 10.1002/adma.201902547 |
| 通讯作者 | Yang, Weishen(yangws@dicp.ac.cn) |
| 英文摘要 | Mixed ionic-electronic conducting oxygen-permeable membranes can rapidly separate oxygen from air with 100% selectivity and low energy consumption. Combining reaction and separation in an oxygen-permeable membrane reactor significantly simplifies the technological scheme and reduces the process energy consumption. Recently, materials design and mechanism investigations have provided insight into the microstructural and interfacial effects. The microstructures of the membrane surfaces and bulk are closely related to the interfacial oxygen exchange kinetics and bulk diffusion kinetics. Therefore, the permeability and stability of oxygen-permeable membranes with a single-phase structure and a dual-phase structure can be adjusted through their microstructural and interfacial designs. Here, recent advances in the development of oxygen permeation models that provide a deep understanding of the microstructural and interfacial effects, and strategies to simultaneously improve the permeability and stability through microstructural and interfacial design are discussed in detail. Then, based on the developed high-performance membranes, highly effective membrane reactors for process intensification and new technology developments are highlighted. The new membrane reactors will trigger innovations in natural gas conversion, ammonia synthesis, and hydrogen-related clean energy technologies. Future opportunities and challenges in the development of oxygen-permeable membranes for oxygen separation and reaction-separation coupling are also explored. |
| WOS关键词 | DUAL-PHASE MEMBRANE ; HOLLOW-FIBER MEMBRANE ; MIXED CONDUCTING MEMBRANES ; SURFACE EXCHANGE KINETICS ; CERAMIC-BASED MEMBRANES ; SELF-HEAT RECUPERATION ; PERMEATION PROPERTIES ; HYDROGEN SEPARATION ; PARTIAL OXIDATION ; AIR SEPARATION |
| 资助项目 | National Natural Science Foundation of China[91545202] ; National Natural Science Foundation of China[U1508203] ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS)[XDB17000000] ; Dalian National Laboratory for Clean Energy (DNL)[DNL180203] ; Dalian National Laboratory for Clean Energy (DNL)[DICP& QIBEBT UN201708] ; Youth Innovation Promotion Association of CAS |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000481322900001 |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Dalian National Laboratory for Clean Energy (DNL) ; Dalian National Laboratory for Clean Energy (DNL) ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Dalian National Laboratory for Clean Energy (DNL) ; Dalian National Laboratory for Clean Energy (DNL) ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Dalian National Laboratory for Clean Energy (DNL) ; Dalian National Laboratory for Clean Energy (DNL) ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Dalian National Laboratory for Clean Energy (DNL) ; Dalian National Laboratory for Clean Energy (DNL) ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/173601]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yang, Weishen |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Xuefeng,Yang, Weishen. Microstructural and Interfacial Designs of Oxygen-Permeable Membranes for Oxygen Separation and Reaction-Separation Coupling[J]. ADVANCED MATERIALS,2019:21. |
| APA | Zhu, Xuefeng,&Yang, Weishen.(2019).Microstructural and Interfacial Designs of Oxygen-Permeable Membranes for Oxygen Separation and Reaction-Separation Coupling.ADVANCED MATERIALS,21. |
| MLA | Zhu, Xuefeng,et al."Microstructural and Interfacial Designs of Oxygen-Permeable Membranes for Oxygen Separation and Reaction-Separation Coupling".ADVANCED MATERIALS (2019):21. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。