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Chiral P,N-ligands for the highly enantioselective addition of diethylzinc to aromatic aldehydes

文献类型：期刊论文

作者Wang, Qiang2; Li, Shuang2; Hou, Chuan-Jin2; Chu, Ting-Ting2; Hu, Xiang-Ping1
刊名APPLIED ORGANOMETALLIC CHEMISTRY
出版日期2019-08-05
页码8
ISSN号0268-2605
关键词addition asymmetric catalysis chiral P N-ligands copper zinc
DOI10.1002/aoc.5108
通讯作者Hou, Chuan-Jin(houcj@dlpu.edu.cn) ; Hu, Xiang-Ping(xiangping@dicp.ac.cn)
英文摘要A new sterically hindered chiral P,N-ligand was synthesized and successfully applied to copper catalyzed asymmetric addition of diethylzinc to aromatic aldehydes. Various aromatic aldehydes can react smoothly to give the corresponding addition products with good to excellent enantioselectivities, which provides a readily accessible method for the preparation of chiral secondary alcohols.
WOS关键词HYDROXY CARBOXYLIC-ACIDS ; CARANE-BASED AMINODIOLS ; ORGANOZINC REAGENTS ; ASYMMETRIC ADDITION ; STEREOSELECTIVE-SYNTHESIS ; GRIGNARD-REAGENTS ; TITANIUM COMPLEX ; ALCOHOL LIGANDS ; MODULAR LIGANDS ; P,N LIGANDS
资助项目Liaoning BaiQianWan Talents Program[201892153] ; Fundamental Research Funds[2017 J027] ; Program of Star of Dalian Youth Science and Technology[2016RQ062] ; National Natural Science Foundation of China[21772196] ; National Natural Science Foundation of China[21572226] ; National Natural Science Foundation of China[21403022]
WOS研究方向Chemistry
语种英语
出版者WILEY
WOS记录号WOS:000479003000001
资助机构Liaoning BaiQianWan Talents Program ; Liaoning BaiQianWan Talents Program ; Fundamental Research Funds ; Fundamental Research Funds ; Program of Star of Dalian Youth Science and Technology ; Program of Star of Dalian Youth Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning BaiQianWan Talents Program ; Liaoning BaiQianWan Talents Program ; Fundamental Research Funds ; Fundamental Research Funds ; Program of Star of Dalian Youth Science and Technology ; Program of Star of Dalian Youth Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning BaiQianWan Talents Program ; Liaoning BaiQianWan Talents Program ; Fundamental Research Funds ; Fundamental Research Funds ; Program of Star of Dalian Youth Science and Technology ; Program of Star of Dalian Youth Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning BaiQianWan Talents Program ; Liaoning BaiQianWan Talents Program ; Fundamental Research Funds ; Fundamental Research Funds ; Program of Star of Dalian Youth Science and Technology ; Program of Star of Dalian Youth Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China
源URL[http://cas-ir.dicp.ac.cn/handle/321008/173687]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Hou, Chuan-Jin; Hu, Xiang-Ping
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Polytech Univ, Sch Light Ind & Chem Enginerring, Dalian 116034, Peoples R China
推荐引用方式
GB/T 7714		 Wang, Qiang,Li, Shuang,Hou, Chuan-Jin,et al. Chiral P,N-ligands for the highly enantioselective addition of diethylzinc to aromatic aldehydes[J]. APPLIED ORGANOMETALLIC CHEMISTRY,2019:8.
APA Wang, Qiang,Li, Shuang,Hou, Chuan-Jin,Chu, Ting-Ting,&Hu, Xiang-Ping.(2019).Chiral P,N-ligands for the highly enantioselective addition of diethylzinc to aromatic aldehydes.APPLIED ORGANOMETALLIC CHEMISTRY,8.
MLA Wang, Qiang,et al."Chiral P,N-ligands for the highly enantioselective addition of diethylzinc to aromatic aldehydes".APPLIED ORGANOMETALLIC CHEMISTRY (2019):8.

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来源：大连化学物理研究所

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