Advanced Porous Membranes with Tunable Morphology Regulated by Ionic Strength of Nonsolvent for Flow Battery
文献类型:期刊论文
作者 | Qiao, Lin1,2; Zhang, Huamin2,3; Lu, Wenjing2; Dai, Qing1,2; Li, Xianfeng2,3 |
刊名 | ACS APPLIED MATERIALS & INTERFACES |
出版日期 | 2019-07-10 |
卷号 | 11期号:27页码:24107-24113 |
ISSN号 | 1944-8244 |
关键词 | vanadium flow battery polybenzimidazole porous membranes tunable morphology ionic strength |
DOI | 10.1021/acsami.9b06142 |
通讯作者 | Li, Xianfeng(lixianfeng@dicp.ac.cn) |
英文摘要 | A simple salt-induced phase separation method is presented to prepare porous polybenzimidazole (PBI) membranes with tunable morphology for vanadium flow batteries (VFBs). This method is based on the traditional nonsolvent-induced phase separation (NIPS) method where salt is introduced into the coagulation bath to change the ionic strength of the nonsolvent. The change of ionic strength will affect the phase separation rate, and finally, the morphology of porous membranes is well tuned from finger-like voids to spongelike pores in site. The membrane with sponge-like pores created multiple barriers to the transfer of vanadium ions, offering the membrane with superhigh selectivity; meanwhile, spongy cells filled with sulfuric acid could provide the membrane with high proton conductivity. As a result, the membrane with sponge-like pores demonstrated a much better performance than that with finger-like voids. The resultant sponge-like porous PBI membrane exhibited a very impressive VFB performance with an energy efficiency of 89.9% at a current density of 80 mA cm(-2), which was close to the highest values ever reported. The battery kept very stable performance even after continuously running for more than 10000 cycles at 160 mA cm(-2), showing excellent stability. This paper provides an easy to scale up and environment-friendly method to fabricate high-performance porous membranes with tunable morphology. |
WOS关键词 | PERFORMANCE ; SELECTIVITY ; PROGRESS |
资助项目 | Natural Science Foundation of China, NSFC[U1808209] ; Strategic Priority Research Program of the CAS[XDA21070100] ; Key Project of Frontier Science, CAS[QYZDB-SSW-JSC032] ; Key R & D Project of Da Lian[2018YF17GX020] |
WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000475532200031 |
资助机构 | Natural Science Foundation of China, NSFC ; Natural Science Foundation of China, NSFC ; Strategic Priority Research Program of the CAS ; Strategic Priority Research Program of the CAS ; Key Project of Frontier Science, CAS ; Key Project of Frontier Science, CAS ; Key R & D Project of Da Lian ; Key R & D Project of Da Lian ; Natural Science Foundation of China, NSFC ; Natural Science Foundation of China, NSFC ; Strategic Priority Research Program of the CAS ; Strategic Priority Research Program of the CAS ; Key Project of Frontier Science, CAS ; Key Project of Frontier Science, CAS ; Key R & D Project of Da Lian ; Key R & D Project of Da Lian ; Natural Science Foundation of China, NSFC ; Natural Science Foundation of China, NSFC ; Strategic Priority Research Program of the CAS ; Strategic Priority Research Program of the CAS ; Key Project of Frontier Science, CAS ; Key Project of Frontier Science, CAS ; Key R & D Project of Da Lian ; Key R & D Project of Da Lian ; Natural Science Foundation of China, NSFC ; Natural Science Foundation of China, NSFC ; Strategic Priority Research Program of the CAS ; Strategic Priority Research Program of the CAS ; Key Project of Frontier Science, CAS ; Key Project of Frontier Science, CAS ; Key R & D Project of Da Lian ; Key R & D Project of Da Lian |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/173914] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Li, Xianfeng |
作者单位 | 1.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Divis Energy Storage, Dalian 116023, Peoples R China 3.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Qiao, Lin,Zhang, Huamin,Lu, Wenjing,et al. Advanced Porous Membranes with Tunable Morphology Regulated by Ionic Strength of Nonsolvent for Flow Battery[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(27):24107-24113. |
APA | Qiao, Lin,Zhang, Huamin,Lu, Wenjing,Dai, Qing,&Li, Xianfeng.(2019).Advanced Porous Membranes with Tunable Morphology Regulated by Ionic Strength of Nonsolvent for Flow Battery.ACS APPLIED MATERIALS & INTERFACES,11(27),24107-24113. |
MLA | Qiao, Lin,et al."Advanced Porous Membranes with Tunable Morphology Regulated by Ionic Strength of Nonsolvent for Flow Battery".ACS APPLIED MATERIALS & INTERFACES 11.27(2019):24107-24113. |
入库方式: OAI收割
来源:大连化学物理研究所
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