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Synthesis of Branched Octahydro-Indene with Methyl Benzaldehyde and Methyl Isobutyl Ketone

文献类型：期刊论文

作者Zhang, Xiaojun1; Han, Fengan1,4; Lin, Sonzhu1; Chen, Fang4; Sun, Mojie1; Liu, Jianjun3; Li, Guangyi4; Tang, Hao4; Wang, Aiqin2,4; Cong, Yu4
刊名ACS SUSTAINABLE CHEMISTRY & ENGINEERING
出版日期2019-07-15
卷号7期号:14页码:12023-12031
关键词Lignocellulose Jet fuel High density Low freezing point Aldol condensation Hydrodeoxygenation
ISSN号2168-0485
DOI10.1021/acssuschemeng.9b00535
通讯作者Li, Ning(lining@dicp.ac.cn)
英文摘要Branched octahydro-indenes were first synthesized with methyl isobutyl ketone (MIBK) and methyl benzaldehyde, which can be obtained from lignocellulose. Initially, C-14 oxygenates were prepared by the aldol condensation reaction of MIBK with methyl benzaldehydes. K2CO3/Al2O3 exhibited the highest activity among the studied solid base catalysts. On the basis of the characterizations, the outstanding activity of K2CO3/Al2O3 was comprehended, because this material has a relatively higher surface area and a larger base site concentration. Subsequently, the aldol condensation products were converted to branched octahydro-indene by hydrodeoxygenation over a Pt/C catalyst. This method is also applicable for the manufacture of C-11-C-13 polycycloalkanes with methyl benzaldehyde and other lignocellulosic ketones. According to our measurements, the polycycloalkanes obtained in this work have low freezing points (227.7 similar to 240.0 K) and high densities (0.857 similar to 0.944 g mL(-1)). Consequently, they may potentially be utilized to raise the volumetric heat values and/or the thermal stability of jet fuels.
WOS关键词DENSITY AVIATION FUEL ; LONG-CHAIN ALKANES ; LIQUID ALKANES ; CYCLIC-KETONES ; JET-FUEL ; BIOMASS ; CATALYST ; ACID ; CYCLOPENTANONE ; DEOXYGENATION
资助项目National Natural Science Foundation of China[21776273] ; National Natural Science Foundation of China[21721004] ; National Natural Science Foundation of China[21690082] ; DNL Cooperation Fund, CAS[DNL180301] ; Science and Technology Research Project of Jilin Province, China[20170204015SF] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020100] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA 21060200] ; National Key Projects for Fundamental Research and Development of China[2016YFA0202801]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Engineering
语种英语
WOS记录号WOS:000475838100013
出版者AMER CHEMICAL SOC
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Science and Technology Research Project of Jilin Province, China ; Science and Technology Research Project of Jilin Province, China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Science and Technology Research Project of Jilin Province, China ; Science and Technology Research Project of Jilin Province, China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Science and Technology Research Project of Jilin Province, China ; Science and Technology Research Project of Jilin Province, China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Science and Technology Research Project of Jilin Province, China ; Science and Technology Research Project of Jilin Province, China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China
源URL[http://cas-ir.dicp.ac.cn/handle/321008/173997]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Li, Ning
作者单位1.Northeast Elect Power Univ, Sci Tech Ctr Clean Convers & High Valued Utilizat, 169 Changchun Rd, Jilin 132012, Jilin, Peoples R China
2.Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, 1295 Dingxi Rd, Shanghai 200050, Peoples R China
4.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Sci & Technol Appl Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714		 Zhang, Xiaojun,Han, Fengan,Lin, Sonzhu,et al. Synthesis of Branched Octahydro-Indene with Methyl Benzaldehyde and Methyl Isobutyl Ketone[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2019,7(14):12023-12031.
APA Zhang, Xiaojun.,Han, Fengan.,Lin, Sonzhu.,Chen, Fang.,Sun, Mojie.,...&Li, Ning.(2019).Synthesis of Branched Octahydro-Indene with Methyl Benzaldehyde and Methyl Isobutyl Ketone.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,7(14),12023-12031.
MLA Zhang, Xiaojun,et al."Synthesis of Branched Octahydro-Indene with Methyl Benzaldehyde and Methyl Isobutyl Ketone".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7.14(2019):12023-12031.

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来源：大连化学物理研究所

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