theactivityandstabilityofpdcl2cncatalystforacetylenehydrochlorination
文献类型:期刊论文
作者 | Li Pan2; Ding Minzheng3; He Limin3; Tie Kai3; Ma Hao1; Pan Xiulian3; Bao Xinhe2 |
刊名 | sciencechinachemistry
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出版日期 | 2018-01-01 |
卷号 | 61期号:4页码:444 |
ISSN号 | 1674-7291 |
英文摘要 | Carbon supported PdCl2 is highly active in catalyzing acetylene hydrochlorination reaction, but deactivates rather quickly. Upon nitrogen doping in the carbon structure, the stability of the PdCl2 catalysts is significantly improved. Furthermore, the results show that 900 A degrees C is a preferred doping temperature. The acetylene conversion keeps above 90% even after 1200 min time on stream whereas the one without nitrogen doping drops to below 10% after 450 min. The stabilizing mechanism of nitrogen doping on catalyst was studied. |
资助项目 | [National Science Foundation of China] |
语种 | 英语 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/174183] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.上海交通大学 2.中国科学技术大学 3.中国科学院大连化学物理研究所 |
推荐引用方式 GB/T 7714 | Li Pan,Ding Minzheng,He Limin,et al. theactivityandstabilityofpdcl2cncatalystforacetylenehydrochlorination[J]. sciencechinachemistry,2018,61(4):444. |
APA | Li Pan.,Ding Minzheng.,He Limin.,Tie Kai.,Ma Hao.,...&Bao Xinhe.(2018).theactivityandstabilityofpdcl2cncatalystforacetylenehydrochlorination.sciencechinachemistry,61(4),444. |
MLA | Li Pan,et al."theactivityandstabilityofpdcl2cncatalystforacetylenehydrochlorination".sciencechinachemistry 61.4(2018):444. |
入库方式: OAI收割
来源:大连化学物理研究所
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